Thermal Treatment of Fluorinated Porous Carbon in Ammonia Flow to Produce a Nitrogen-Doped Support for Highly Dispersed Nickel Effectively Catalyzing Formic Acid Dehydrogenation | Sciact - CRIS-system of Boreskov Institute of Catalysis

Thermal Treatment of Fluorinated Porous Carbon in Ammonia Flow to Produce a Nitrogen-Doped Support for Highly Dispersed Nickel Effectively Catalyzing Formic Acid Dehydrogenation Full article

Journal

Materials Today Chemistry
ISSN: 2468-5194

Output data

Year: 2025, Volume: 47, Article number : 102786, Pages count : 14 DOI: 10.1016/j.mtchem.2025.102786

Tags

Room-temperature fluorination; Ammonia treatment; N-doped porous carbon; Ni single-atoms; Formic acid dehydrogenation

Authors

Nishchakova Alina D. ¹ , Bulushev Dmitri A. ² , Fedoseeva Yuliya V. ¹ , Tsygankova Alphiya R. ¹ , Trubina Svetlana V. ¹ , Kriventsov Vladimir V. ³ , Stonkus Olga A. ² , Okotrub Alexander V. ¹ , Bulusheva Lyubov G. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090, Novosibirsk, Russia
2	Boreskov Institute of Catalysis SB RAS, 5 Acad. Lavrentiev Ave., 630090, Novosibirsk, Russia
3	Synchrotron Radiation Facility – Siberian Circular Photon Source “SKIF”, 1 pr. Nikolsky, r.p. Kol'tsovo, 630559, Novosibirsk, Russia

Funding (2)

1	Ministry of Science and Higher Education of the Russian Federation	FWUR-2024-0036
2	Ministry of Science and Higher Education of the Russian Federation	FWUZ-2025-0004 (125021001790-0)(075-03-2025-190)

Nitrogen-doped carbon attracts researchers as a catalyst support due to its ability to provide high dispersion of deposited metal, which can show improved properties in various catalytic reactions as compared to the metal on nitrogen-free carbon supports. Here, we developed a procedure for modification of a porous carbon material by fluorination with bromine trifluoride vapor at room temperature followed by heating in gaseous ammonia to produce a nitrogen-doped carbon support for nickel catalyst. The obtained support has a specific surface area of 1030 m2/g and a total nitrogen content of 4.8 at.%, with half of it in the form of pyridinic nitrogen, which is necessary for stabilization of nickel atoms. These characteristics of the support allow a simple impregnation method to achieve a content of nickel single-atom sites up to 4.9 wt.%. Increasing the metal content to 7.4 wt.% leads to the formation of nickel particles with an average size of less than 1 nm. The catalysts were tested in the decomposition reaction of gaseous formic acid and showed high (>99 %) and stable selectivity toward hydrogen production.

Nishchakova A.D. , Bulushev D.A. , Fedoseeva Y.V. , Tsygankova A.R. , Trubina S.V. , Kriventsov V.V. , Stonkus O.A. , Okotrub A.V. , Bulusheva L.G.
Thermal Treatment of Fluorinated Porous Carbon in Ammonia Flow to Produce a Nitrogen-Doped Support for Highly Dispersed Nickel Effectively Catalyzing Formic Acid Dehydrogenation
Materials Today Chemistry. 2025. V.47. 102786 :1-14. DOI: 10.1016/j.mtchem.2025.102786 Scopus

Submitted:	Feb 20, 2025
Accepted:	May 29, 2025
Published online:	Jun 10, 2025
Published print:	Jul 1, 2025

Scopus:

2-s2.0-105007559018

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