Production of Hydrogen from Methane over Nickel-Copper Oxide Catalysts Prepared via Mechanochemical Activation under Varied Conditions | Sciact - CRIS-system of Boreskov Institute of Catalysis

Production of Hydrogen from Methane over Nickel-Copper Oxide Catalysts Prepared via Mechanochemical Activation under Varied Conditions Full article

Journal

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Output data

Year: 2025, Article number : 150082, Pages count : 12 DOI: 10.1016/j.ijhydene.2025.150082

Tags

hydrogen production; carbon nanofibers; catalytic chemical vapor deposition of methane; nickel-copper catalyst; mechanochemical activation

Authors

Shivtsov Danil M. ¹ , Veselov Grigory B. ¹ , Afonnikova Sofya D. ¹ , Ayupov Artem B. ¹ , Shubin Yury V. ² , Bauman Yury I. ¹ , Mishakov Ilya V. ¹ , Shelepova Ekaterina V. ¹ , Vedyagin Aleksey A. ¹

Affiliations

1	Boreskov Institute of Catalysis, 5 ac. Lavrentieva Ave, 630090, Novosibirsk, Russia
2	Nikolaev Institute of Inorganic Chemistry SB RAS, 3 ac. Lavrentieva Ave, 630090, Novosibirsk, Russia

Funding (1)

Russian Science Foundation
Министерство науки и инновационной политики Новосибирской области

24-29-20095

Production of hydrogen from natural gas remains to be an actual task. In a present study, a series of NiO-CuO-Al(OH)3 catalysts was prepared using a mechanochemical activation method under varied conditions. Among the considered parameters are centrifugal acceleration value (an), the motion mode of the milling balls, and their diameter. Although these parameters did not affect the phase composition of the obtained powders noticeably, they influenced the dispersion and distribution uniformity of the components and, thus, affected the catalytic activity in the catalytic chemical vapor deposition of methane. At an = 40 G, the prepared powders possess the maximum possible dispersion and distribution uniformity of metal oxides. In the case of the optimized preparation conditions, the achieved hydrogen productivity was as high as 215 Nm3/(kgcat×h). Carbon nanofibers, which are the solid-phase product of the process, possess a stacked and coaxial-conical structure and have a diameter of 10-120 nm.

Shivtsov D.M. , Veselov G.B. , Afonnikova S.D. , Ayupov A.B. , Shubin Y.V. , Bauman Y.I. , Mishakov I.V. , Shelepova E.V. , Vedyagin A.A.
Production of Hydrogen from Methane over Nickel-Copper Oxide Catalysts Prepared via Mechanochemical Activation under Varied Conditions
International Journal of Hydrogen Energy. 2025. 150082 :1-12. DOI: 10.1016/j.ijhydene.2025.150082

Submitted:	Apr 30, 2025
Accepted:	Jun 17, 2025

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