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Suppression of the Magnetic Transition in Ultrasmall ϵ-Fe2O3 Nanoparticles: the Size Effect from Nuclear Forward Scattering Data Full article

Journal Journal of Experimental and Theoretical Physics Letters (JETP Letters)
ISSN: 0021-3640 , E-ISSN: 1090-6487
Output data Year: 2025, Volume: 121, Number: 10, Pages: 800–805 Pages count : 6 DOI: 10.1134/S0021364025606396
Tags VERWEY TRANSITION; MORIN TRANSITION; HIGH-TEMPERATURE; EPSILON-Fe2O3; MOSSBAUER; Fe3O4
Authors Knyazev Yu.V. 1 , Balaev D.A. 1 , Dubrovskiy A.A. 1 , Semenov S.V. 1 , Kirillov V.L. 2 , Martyanov O.N. 2
Affiliations
1 Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036 Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (2)

1 Ministry of Science and Higher Education of the Russian Federation
2 Ministry of Science and Higher Education of the Russian Federation ГЗ-2024-2028

Abstract: The features of the magnetic structure of ultrasmall ϵ-Fe2O3 nanoparticles have been studied by the nuclear forward scattering technique using synchrotron radiation. The sample consists of isolated ϵ-Fe2O3 nanoparticles with an average size of nm immobilized in a SiO2 xerogel matrix. The time-domain spectra have been measured in the temperature range of 4–300 K in zero external magnetic field and field T applied in the longitudinal direction. The character of the change in the hyperfine field Hhf as a function of the external magnetic field is the same in the entire temperature range: unlike large ϵ-Fe2O3 particles, a monotonic increase in Hhf is observed in the external field. These results indicate that there is no magnetic transition in the temperature range of 80–150 K for ultrasmall (smaller than 9 nm) ϵ-Fe2O3 particles, and the magnetic structure is noncollinear in the range of 4–300 K.
Cite: Knyazev Y.V. , Balaev D.A. , Dubrovskiy A.A. , Semenov S.V. , Kirillov V.L. , Martyanov O.N.
Suppression of the Magnetic Transition in Ultrasmall ϵ-Fe2O3 Nanoparticles: the Size Effect from Nuclear Forward Scattering Data
Journal of Experimental and Theoretical Physics Letters (JETP Letters). 2025. V.121. N10. P.800–805. DOI: 10.1134/S0021364025606396 WOS Scopus OpenAlex
Original: Князев Ю.В. , Балаев Д.А. , Дубровский А.А. , Семёнов С.В. , Кириллов В.Л. , Мартьянов О.Н.
Подавление магнитного перехода в ультрамалых наночастицах ∈-FE2O3 - размерный эффект по данным метода ядерного рассеяния вперед
Письма в Журнал экспериментальной и теоретической физики. 2025. Т.121. №9-10. С.839-845. DOI: 10.31857/S0370274X25050202 РИНЦ
Dates:
Submitted: Apr 9, 2025
Accepted: Apr 22, 2025
Published print: May 1, 2025
Published online: Jul 14, 2025
Identifiers:
Web of science: WOS:001528992300007
Scopus: 2-s2.0-105010694082
OpenAlex: W4412399313
Citing: Пока нет цитирований
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