Synthesis of Organic Carbonates over Metal Azolate Frameworks via the Carbonate Interchange Process Using Catechol Carbonate and Alcohols | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis of Organic Carbonates over Metal Azolate Frameworks via the Carbonate Interchange Process Using Catechol Carbonate and Alcohols Full article

Journal

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Output data

Year: 2025, Article number : 120489, Pages count : 10 DOI: 10.1016/j.apcata.2025.120489

Tags

Organic carbonates; Catechol carbonate; Alcohols; Base catalysis; Metal-azolate frameworks

Authors

Timofeeva Maria N. ^1,2 , Isaeva Vera I. ² , Arkhipov Danil A. ² , Prikhod’ko Sergey A. ¹ , Lukoyanov Ivan A. ¹ , Panchenko Valentina N. ¹ , Mel’gunova Elena A. ¹ , Jhung Sung Hwa ³

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2	N.D. Zelinsky Institute of Organic Chemistry RAS, Prospekt Leninski 47, 119991, Moscow, Russian Federation
3	Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, Republic of Korea

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

FWUR-2024-0035

Metal-azolate frameworks (MAFs) is a promising sub-class of metal-organic frameworks (MOFs) due to their remarkable porosity, bifunctional acid-base character, and satisfactory thermal/chemical stability. Herein, synthesis of organic carbonates via the carbonate interchange reaction (CIR) using catechol carbonate (CC) and alcohols, namely cyclohexanol and hexanol-1 was demonstrated for the first time using MAF catalysts, such as MAF-4 (synonym ZIF-8), MAF-5, and MAF-6 obtained via synthesis under ambient conditions. CIR process was carried out at alcohol/CC molar ratio of 14.3, 10 wt.% of MAFs (based on the weight of CC) and 60-110 oC under thermal heating and microwave (MW)-activation. The major CIR products were dicyclohexylcarbonate and dihexylcarbonate. Reaction rates depended on the strength of basic sites in the MAF materials and decreased in the order MAF-5 > MAF-6 > MAF-4. At the same time, reducing the channel size of MAF catalysts resulted in the decreased yields of organic carbonates in the following order MAF-6 > MAF-5 > MAF-4. The CIR process, assisted by microwave activation of the reaction mixture, offered several advantages over conventional thermal heating, including higher organic carbonate yields, shorter reaction times, and lower reaction temperatures

Timofeeva M.N. , Isaeva V.I. , Arkhipov D.A. , Prikhod’ko S.A. , Lukoyanov I.A. , Panchenko V.N. , Mel’gunova E.A. , Jhung S.H.
Synthesis of Organic Carbonates over Metal Azolate Frameworks via the Carbonate Interchange Process Using Catechol Carbonate and Alcohols
Applied Catalysis A: General. 2025. 120489 :1-10. DOI: 10.1016/j.apcata.2025.120489 WOS Scopus AN OpenAlex

Submitted:	Jun 10, 2025
Accepted:	Aug 2, 2025
Published online:	Aug 5, 2025

Web of science:	WOS:001547305400004
Scopus:	2-s2.0-105012535640
Chemical Abstracts:	2025:1935327
OpenAlex:	W4412979922

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