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Structured Catalysts for Steam and Autothermal Reforming of Ethanol to Synthesis Gas. Part 1: Synthesis and Catalytic Properties Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2025, Volume: 17, Number: 3, Pages: 242-250 Pages count : 9 DOI: 10.1134/s207005042570014x
Tags autothermal reforming, steam reforming, ethanol, hydrogen, structured catalyst
Authors Rogozhnikov V.N. 1 , Potemkin D.I. 1 , Stonkus O.A. 1 , Shefer K.I. 1 , Salanov A.N. 1 , Pakharukova V.P. 1 , Snytnikov P.V. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (1)

1 Russian Science Foundation 22-79-00208

Abstract: Steam and autothermal ethanol reforming provides the production of synthesis gas suitable for use both in fuel cells and as a feedstock as a feedstock the chemical industry. The effective occurrence of these reactions requires heat transfer control. In the case of the endothermic steam reforming of ethanol, the problem of heat transfer from the reactor walls to the catalyst bed arises. For the thermoneutral autothermal reforming (steam–air conversion) of ethanol, the heat evolved in the frontal part of the catalyst bed due to ethanol oxidation by oxygen should be redistributed along the catalyst bed to compensate for the endothermic effect of ethanol steam reforming. Structured catalysts based on heat-conducting substrates—metal gauzes, metal foam, and other supports—are well suited to solving these problems. These catalysts are represented by a complex composite material with a multilevel “structured metal substrate–structural oxide component–active oxide–metal/alloy nanoparticle” structure, which combines the functions of a heat exchanger, a flow distributor, and a catalyst. This paper describes results of synthesizing structured Pt-, Rh-, Pd-, Ru-, Ni-, and Co-containing catalysts supported on a FeCrAl gauze and studying their catalytic properties.
Cite: Rogozhnikov V.N. , Potemkin D.I. , Stonkus O.A. , Shefer K.I. , Salanov A.N. , Pakharukova V.P. , Snytnikov P.V.
Structured Catalysts for Steam and Autothermal Reforming of Ethanol to Synthesis Gas. Part 1: Synthesis and Catalytic Properties
Catalysis in Industry. 2025. V.17. N3. P.242-250. DOI: 10.1134/s207005042570014x WOS Scopus РИНЦ OpenAlex
Original: Рогожников В.Н. , Потемкин Д.И. , Стонкус О.А. , Шефер К.И. , Саланов А.Н. , Пахарукова В.П. , Снытников П.В.
Структурированные катализаторы паровой и паровоздушной конверсий этанола в синтез-газ. I. Приготовление и каталитические свойства
Катализ в промышленности. 2024. Т.24. №5. С.13-23. DOI: 10.18412/1816-0387-2024-6-13-23 РИНЦ AN OpenAlex
Dates:
Submitted: Apr 8, 2024
Accepted: May 8, 2024
Published online: Jul 31, 2025
Published print: Sep 1, 2025
Identifiers:
Web of science: WOS:001542184700005
Scopus: 2-s2.0-105012261300
Elibrary: 82714920
OpenAlex: W4412790391
Citing: Пока нет цитирований
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