Titanium–Magnesium Catalysts for Propylene Polymerization: Synthesis with Ethers and Subsequent Adding of Dibutyl Phthalate Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2025, Volume: 66, Number: 3, Pages: 330-341 Pages count : 12 DOI: 10.1134/s0023158424602742 | ||
| Tags | Ziegler–Natta catalysts, titanium-magnesium catalysts, MgCl2 formation, propylene polymerization | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0037 |
Abstract:
Propylene polymerization titanium–magnesium catalysts in the presence of ethers are synthesized. It is shown that aliphatic ethers and 1.1-diethers are participated in the formation of magnesium chloride although they are not contained in catalysts. Aromatic ethers (except methyl phenyl ether) are ineffective in the MgCl2 formation. Subsequent adding of the phthalate (DBP/Mg = 0.05 mol) lead to the synthesis of the phtalate titanium–magnesium catalyst which in the case of aliphatic ethers and 1.1-diethers have catalytic properties higher than the titanium–magnesium catalyst for comparison (DBP/Mg = 0.05 mol) and close ones (for some ethers) to the standard titanium–magnesium catalysts (DBP/Mg = 0.2 mol). Comparative analysis of the composition of phthalate titanium–magnesium catalysts prepared using ethers or ketones and X-ray data indicate a close size of MgCl2 crystallites in both cases. The composition of titanium–magnesium catalysts synthesized in the presence of ethers is consistent with the distribution of dimeric TiCl4 complexes alternating with chlorine vacancies (…□TiTi□TiTi…) on the lateral cuts 104.
Cite:
Maslov D.K.
, Bukatov G.D.
Titanium–Magnesium Catalysts for Propylene Polymerization: Synthesis with Ethers and Subsequent Adding of Dibutyl Phthalate
Kinetics and Catalysis. 2025. V.66. N3. P.330-341. DOI: 10.1134/s0023158424602742 WOS Scopus РИНЦ AN OpenAlex
Titanium–Magnesium Catalysts for Propylene Polymerization: Synthesis with Ethers and Subsequent Adding of Dibutyl Phthalate
Kinetics and Catalysis. 2025. V.66. N3. P.330-341. DOI: 10.1134/s0023158424602742 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Dec 25, 2024 |
| Accepted: | Apr 30, 2025 |
| Published online: | Sep 4, 2025 |
Identifiers:
| Web of science: | WOS:001566661700005 |
| Scopus: | 2-s2.0-105015135895 |
| Elibrary: | 82850476 |
| Chemical Abstracts: | 2025:2208972 |
| OpenAlex: | W4414004031 |
Citing:
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