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Hollow Alumina Spheres: Fabrication, Characterization, and Their Potential for Operando Magnetic Resonance Full article

Journal Analytical Chemistry
ISSN: 0003-2700 , E-ISSN: 1520-6882
Output data Year: 2025, DOI: 10.1021/acs.analchem.5c01321
Tags Alkyls; Hollow spheres; Hollow structures; Nuclear magnetic resonance spectroscopy; Oxides
Authors Kononenko Elizaveta S. 1,2 , Skovpin Ivan V. 1 , Burueva Dudari B. 1 , Rogozhnikov Vladimir N. 3 , Shefer Kristina I. 3 , Salanov Alexei N. 3 , Koptyug Igor V. 1
Affiliations
1 International Tomography Center SB RAS, 630090 Novosibirsk, Russia
2 Novosibirsk State University, 630090 Novosibirsk, Russia
3 Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation FWUR-2024-0033

Abstract: Magnetic resonance (MR) techniques, including nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI), are powerful noninvasive tools for in situ and operando investigations of catalytic processes. However, their application to heterogeneous catalytic systems, particularly those involving gaseous reactants, is often limited by magnetic field inhomogeneities caused by conventional solid catalyst supports. In this work, we present hollow spheres as advanced porous catalyst supports that address this issue. Hollow alumina spheres were prepared via template synthesis and characterized using physicochemical methods, including XRD, BET, SEM, and optical microscopy, confirming their η-Al2O3 phase, high surface area (∼302 m2/g), and stable hollow geometry with thin walls (∼0.05 mm). Unlike conventional bulk catalyst particles, these hollow alumina spheres do not cause significant distortions of magnetic field homogeneity. As a result, well-resolved 1H NMR spectra and high-quality MR images of gases and solutions in a granular bed were obtained, greatly enhancing precision in catalytic reactor characterization by MR techniques.
Cite: Kononenko E.S. , Skovpin I.V. , Burueva D.B. , Rogozhnikov V.N. , Shefer K.I. , Salanov A.N. , Koptyug I.V.
Hollow Alumina Spheres: Fabrication, Characterization, and Their Potential for Operando Magnetic Resonance
Analytical Chemistry. 2025. DOI: 10.1021/acs.analchem.5c01321 WOS PMID OpenAlex
Dates:
Submitted: Mar 4, 2025
Accepted: Sep 15, 2025
Published online: Sep 22, 2025
Identifiers:
Web of science: WOS:001576268200001
PMID: 40981709
OpenAlex: W4414408330
Citing: Пока нет цитирований
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