Bioinspired Oxidations of C–H Groups Mediated by Nonheme Complexes of Late Transition Metals Co, Ni, and Cu | Sciact - CRIS-система Института катализа

Bioinspired Oxidations of C–H Groups Mediated by Nonheme Complexes of Late Transition Metals Co, Ni, and Cu Обзор

Журнал

ACS Catalysis
ISSN: 2155-5435

Вых. Данные

Год: 2025, Том: 15, Номер: 20, Страницы: 17525-17547 Страниц : 23 DOI: 10.1021/acscatal.5c05705

Ключевые слова

biomimetic catalysis, C–H activation, hydrogen peroxide, oxidation, oxo-wall, oxygenases, mechanism

Авторы

Lyakin Oleg Y. ¹ , Talsi Evgenii P. ¹ , Bryliakov Konstantin P. ²

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia
2	Zelinsky Institute of Organic Chemistry RAS, Moscow 119991, Russia

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)

FWUR-2024-0032

Deliberately selective activation and functionalization of the abundant and poorly reactive C–H bonds have long been a major challenge, as well as inspiration, for synthetic and catalytic chemists. In recent years, this interest has boosted due to the growing demands of medicinal chemistry for the efficient, environmentally benign, and atom-economic methods of late-stage functionalization/molecular editing of complex organic substrates. One promising general approach relies on biomimetic, or bioinspired, transition metal-based catalysts that mimic the catalytic reactivity of naturally occurring metalloenzymes oxygenases. So far, Fe- and Mn-based catalysts have dominated this area; however, complexes of late transition metals, such as Co, Ni, and Cu, have been attracting increasing attention in both synthetic and mechanistic aspects, mostly due to their tunable catalytic reactivity complementing the reactivity patterns of their Fe and Mn counterparts. Another point of interest is their location in the periodic table, beyond the so-called “oxo-wall”─which entails peculiarities in the electronic structures of the active species responsible for C–H activation and oxygen transfer. This contribution is aimed at surveying the existing systems based on bioinspired nonheme complexes of Co, Ni, and Cu, discussing their catalytic reactivity patterns, the nature of the active species, and the overall mechanisms of catalysis. Contributions since 2005 are considered.

Lyakin O.Y. , Talsi E.P. , Bryliakov K.P.
Bioinspired Oxidations of C–H Groups Mediated by Nonheme Complexes of Late Transition Metals Co, Ni, and Cu
ACS Catalysis. 2025. V.15. N20. P.17525-17547. DOI: 10.1021/acscatal.5c05705 WOS Scopus CAPlus OpenAlex

Поступила в редакцию:	13 авг. 2025 г.
Принята к публикации:	23 сент. 2025 г.
Опубликована online:	7 окт. 2025 г.
Опубликована в печати:	17 окт. 2025 г.

Web of science:	WOS:001588870300001
Scopus:	2-s2.0-105018299111
Chemical Abstracts:	2025:2478494
OpenAlex:	W4414877862

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