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Honeycomb Supported LaFe1 – xNixO3 (x = 0, 0.6, 1) Perovskite Catalysts for High-Temperature N2O Decomposition Научная публикация

Журнал Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Вых. Данные Год: 2025, DOI: 10.1134/S0023158425600634
Ключевые слова perovskite, Pechini, decomposition of N2O, honeycomb corundum support
Авторы Isupova L.A. 1 , Ivanova Yu.A. 1 , Salanov A.N. 1
Организации
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090 Russia

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) FWUR-2024-0038

Реферат: Using the Pechini method, LaFe1 – xNixO3 (x = 0, 0.6, 1) perovskite-containing catalysts supported on a monolith corundum support were prepared and studied in the reaction of high-temperature decomposition of nitrous oxide. It is shown that the supported catalysts can be arranged in the following order by activity: LaFeO3/α-Al2O3 > LaFe0.4Ni0.6O3/α-Al2O3 > LaNiO3/α-Al2O3, which differs from the activity order of perovskites without a support. The change in the activity order is due to the interaction of the impregnating solution with the support, as a result of which an admixture of the nickel aluminate phase, inactive in this reaction, can be formed in nickel-containing catalysts. The LaFeO3/α-Al2O3 catalyst with an active component content of ~5%, even with a fragment height of 20 mm (and a contact time of 0.06 s), provides a high (~84%) conversion of nitrous oxide, due to the possible presence of an impurity of the dispersed phase of active Fe2O3 as well.
Библиографическая ссылка: Isupova L.A. , Ivanova Y.A. , Salanov A.N.
Honeycomb Supported LaFe1 – xNixO3 (x = 0, 0.6, 1) Perovskite Catalysts for High-Temperature N2O Decomposition
Kinetics and Catalysis. 2025. DOI: 10.1134/S0023158425600634
Даты:
Поступила в редакцию: 20 июн. 2025 г.
Принята к публикации: 18 июл. 2025 г.
Опубликована online: 10 нояб. 2025 г.
Идентификаторы БД: Нет идентификаторов
Цитирование в БД: Пока нет цитирований
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