In Situ SAXS Study of the Formation of Palladium Polynuclear Hydroxo Complexes Научная публикация
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Вых. Данные | Год: 2025, Том: 66, Номер: 4, Страницы: 449-455 Страниц : 7 DOI: 10.1134/S0023158425600294 | ||
| Ключевые слова | palladium, polynuclear hydroxo complexes, SAXS, in situ, Ostwald ripening, Gaussian chain | ||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Министерство науки и высшего образования Российской Федерации (с 15 мая 2018) | FWUR-2024-0032 |
Реферат:
The process of formation of palladium hydroxo complexes during hydrolysis of palladium chloride in an alkaline medium was investigated by the in situ small-angle X-ray scattering (SAXS) technique. It was shown that the aging process of palladium hydroxo complexes corresponded to the Ostwald ripening mechanism. The time dependent particle shapes and particle size distributions were determined for the palladium hydroxo complexes in solution. It was found that loose particles described by the form factor of Gaussian chains were formed in the solution at the beginning of the aging process. After they reached a certain size, the process of chain folding and transformation into particles with a compact shape took place. Further, compact particles aggregated to form larger secondary aggregates.
Библиографическая ссылка:
Larichev Y.V.
In Situ SAXS Study of the Formation of Palladium Polynuclear Hydroxo Complexes
Kinetics and Catalysis. 2025. V.66. N4. P.449-455. DOI: 10.1134/S0023158425600294 WOS Scopus РИНЦ OpenAlex
In Situ SAXS Study of the Formation of Palladium Polynuclear Hydroxo Complexes
Kinetics and Catalysis. 2025. V.66. N4. P.449-455. DOI: 10.1134/S0023158425600294 WOS Scopus РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 8 апр. 2025 г. |
| Принята к публикации: | 25 июн. 2025 г. |
| Опубликована в печати: | 1 авг. 2025 г. |
| Опубликована online: | 13 нояб. 2025 г. |
Идентификаторы БД:
| Web of science: | WOS:001613737200006 |
| Scopus: | 2-s2.0-105021402994 |
| РИНЦ: | 83185537 |
| OpenAlex: | W7104555339 |
Цитирование в БД:
Пока нет цитирований