Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols | Sciact - CRIS-система Института катализа

Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols Научная публикация

Журнал

New Journal of Chemistry
ISSN: 1144-0546 , E-ISSN: 1369-9261

Вых. Данные

Год: 2026, Том: 50, Номер: 2, Страницы: 676-685 Страниц : 10 DOI: 10.1039/d5nj03435c

Ключевые слова

THERMAL-DEGRADATION; HYDRODESULFURIZATION; CONVERSION; PATHWAYS; DONOR

Авторы

Romanov Alexander ¹ , Nesterov Nikolai ¹ , Pakharukova Vera ¹ , Prosvirin Igor ¹ , Salomatina Anna ¹ , Klimov Oleg ¹ , Martyanov Oleg ¹

Организации

1	Boreskov Institute of Catalysis SB RAS, Academician Lavrentiev ave. 5, Novosibirsk 630090, Russia

The influence of the nature of alcohols (MeOH, EtOH, 1-PrOH, 2-PrOH, 2-BuOH, and CyOH) on the process of hydrodechlorination of chlorobenzene (PhCl) under conditions of hydrogen transfer in the presence of (Ni, Co)Mo sulfide catalysts was investigated. It was found that the efficiency of chlorine removal depends on the nature of the alcohol: 2-PrOH > 2-BuOH > MeOH > CyOH > 1-PrOH > EtOH. Minor products (alkylbenzenes) were observed only for secondary alcohols such as 2-PrOH, 2-BuOH, and CyOH. The results demonstrate the potential of alcohols (2-PrOH, 2-BuOH, CyOH, and MeOH) as alternative hydrogen donors for the environmentally safe processing of organochlorine waste.

Romanov A. , Nesterov N. , Pakharukova V. , Prosvirin I. , Salomatina A. , Klimov O. , Martyanov O.
Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols
New Journal of Chemistry. 2026. V.50. N2. P.676-685. DOI: 10.1039/d5nj03435c WOS Scopus OpenAlex CAPlus

Поступила в редакцию:	26 авг. 2025 г.
Принята к публикации:	26 нояб. 2025 г.
Опубликована online:	12 дек. 2025 г.
Опубликована в печати:	12 янв. 2026 г.

≡ Web of science:	WOS:001637872100001
≡ Scopus:	2-s2.0-105024781757
≡ OpenAlex:	W7114912145
≡ Chemical Abstracts:	2025:3068711

≡ OpenAlex	Нет цитирований	Сбор данных от 08.02.2026
≡ Scopus	Нет цитирований	Сбор данных от 08.02.2026