Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols Научная публикация
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New Journal of Chemistry
ISSN: 1144-0546 , E-ISSN: 1369-9261 |
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| Вых. Данные | Год: 2026, Том: 50, Номер: 2, Страницы: 676-685 Страниц : 10 DOI: 10.1039/d5nj03435c | ||
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Реферат:
The influence of the nature of alcohols (MeOH, EtOH, 1-PrOH, 2-PrOH, 2-BuOH, and CyOH) on the process of hydrodechlorination of chlorobenzene (PhCl) under conditions of hydrogen transfer in the presence of (Ni, Co)Mo sulfide catalysts was investigated. It was found that the efficiency of chlorine removal depends on the nature of the alcohol: 2-PrOH > 2-BuOH > MeOH > CyOH > 1-PrOH > EtOH. Minor products (alkylbenzenes) were observed only for secondary alcohols such as 2-PrOH, 2-BuOH, and CyOH. The results demonstrate the potential of alcohols (2-PrOH, 2-BuOH, CyOH, and MeOH) as alternative hydrogen donors for the environmentally safe processing of organochlorine waste.
Библиографическая ссылка:
Romanov A.
, Nesterov N.
, Pakharukova V.
, Prosvirin I.
, Salomatina A.
, Klimov O.
, Martyanov O.
Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols
New Journal of Chemistry. 2026. V.50. N2. P.676-685. DOI: 10.1039/d5nj03435c WOS Scopus CAPlus OpenAlex
Hydrogen Transfer Reactions in the Presence of (Ni, Co)Mo-Sulfide Catalysts as an Effective Tool for Hydrodechlorination: The Role of the Nature of Lower Alcohols
New Journal of Chemistry. 2026. V.50. N2. P.676-685. DOI: 10.1039/d5nj03435c WOS Scopus CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 26 авг. 2025 г. |
| Принята к публикации: | 26 нояб. 2025 г. |
| Опубликована online: | 12 дек. 2025 г. |
| Опубликована в печати: | 12 янв. 2026 г. |
Идентификаторы БД:
| Web of science: | WOS:001637872100001 |
| Scopus: | 2-s2.0-105024781757 |
| Chemical Abstracts: | 2025:3068711 |
| OpenAlex: | W7114912145 |
Цитирование в БД:
| БД | Цитирований |
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| OpenAlex | Нет цитирований |
| Scopus | Нет цитирований |