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ATR-FTIR Spectroscopic Study of CO2 Sorption Depending on the Ionogel Solid Matrix Type Full article

Journal Langmuir
ISSN: 0743-7463 , E-ISSN: 1520-5827
Output data Year: 2025, DOI: 10.1021/acs.langmuir.5c04470
Tags Ionogel, ionic liquid, CO2, sorption, ATR-FTIR spectroscopy
Authors Kovalev Evgeny P. 1 , Martyanov Oleg N. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russia

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation FWUR-2024-0032

Abstract: Ionogels representing gels based on ionic liquids (ILs) are of great interest as adsorbent materials believed to have great potential for CO2 capture. However, there is limited information regarding the influence of the network matrix peculiarities on CO2 sorption by ionogels. Both in situ attenuated total reflectance Fourier transform infrared (ATR-FTIR) and FTIR imaging spectroscopy have been applied to investigate the influence of the chemical nature and the structure of the ionogel support matrix on the spectral characteristics of sorbed CO2. A range of ionogels has been prepared, and the distribution of the IL on the matrix surface has been considered. An analysis of the sorbed CO2 spectra is given, with special attention paid to side processes occurring during sorption. It has been shown that textural properties of the support matrix have a greater impact than the chemical nature in terms of CO2 sorption.
Cite: Kovalev E.P. , Martyanov O.N.
ATR-FTIR Spectroscopic Study of CO2 Sorption Depending on the Ionogel Solid Matrix Type
Langmuir. 2025. DOI: 10.1021/acs.langmuir.5c04470AN PMID OpenAlex
Dates:
Submitted: Aug 25, 2025
Accepted: Dec 11, 2025
Published online: Dec 19, 2025
Identifiers:
Chemical Abstracts: 2025:3148193
PMID: 41416628
OpenAlex: W7116121580
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