Phenol Hydroxylation with Nitrous Oxide Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2012, Volume: 4, Number: 3, Pages: 168-173 Pages count : 6 DOI: 10.1134/S207005041203004X | ||
| Tags | Dihydroxybenzenes, Nitrous oxide, Phenol hydroxylation, Zeolite catalysts | ||
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| Affiliations |
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Abstract:
Phenol hydroxylation with nitrous oxide opens up a new, promising way to the gas-phase synthesis of dihydroxybenzenes, which are among the most important semiproducts of contemporary organic chemistry. A process based on this reaction could provide an alternative to the existing liquid-phase processes employing hydrogen peroxide as the oxidizer. Here, we report phenol oxidation with nitrous oxide over zeolite MFI at 450–500°C and a residence time of 1.70–3.4 s. The dihydrobenzenes production rate per unit weight of the catalyst is 2.3 mmol/(g h). The process involving nitrous oxide is superior to the other technologies in terms of oxidizer consumption efficiency and dihydroxybenzene isomer proportions. Specifically, the nitrous oxide conversion into dihydroxybenzenes is 74% and hydroquinone-to-catechol ratio in the reaction product is 1.2–1.4.
Cite:
Ivanov D.P.
, Pirutko L.V.
Phenol Hydroxylation with Nitrous Oxide
Catalysis in Industry. 2012. V.4. N3. P.168-173. DOI: 10.1134/S207005041203004X WOS Scopus РИНЦ OpenAlex
Phenol Hydroxylation with Nitrous Oxide
Catalysis in Industry. 2012. V.4. N3. P.168-173. DOI: 10.1134/S207005041203004X WOS Scopus РИНЦ OpenAlex
Original:
Иванов Д.П.
, Пирютко Л.В.
Гидроксилирование фенола закисью азота
Катализ в промышленности. 2012. №3. С.9-15. РИНЦ ANCAN
Гидроксилирование фенола закисью азота
Катализ в промышленности. 2012. №3. С.9-15. РИНЦ ANCAN
Dates:
| Published print: | Jul 1, 2012 |
| Published online: | Sep 15, 2012 |
Identifiers:
| Web of science: | WOS:000433661100003 |
| Scopus: | 2-s2.0-84866503207 |
| Elibrary: | 20482947 |
| OpenAlex: | W2074930701 |