Oxo Complexes of High-Valence Iron in Oxidation Catalysis Review
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2012, Volume: 53, Number: 6, Pages: 694-713 Pages count : 20 DOI: 10.1134/S0023158412050084 | ||||
| Tags | Kinetic Isotope Effect; Cyclooctene; TPEN; Nonheme Iron; Talsi | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 12-03-00782 |
| 2 | Russian Foundation for Basic Research | 12-03-31709 |
Abstract:
This review deals with oxo complexes of high-valence iron (oxoferryl, or simply ferryl complexes), which play an important role in the selective oxidation of hydrocarbons and other organic compounds. The efficiency and high selectivity of natural oxygenases stimulates researchers to design chemical analogues of these systems. Since the advantages of biological and biomimetic oxidation are due to the participation of ferryl intermediates, we will consider the ways of obtaining relatively stable oxo complexes of high-valence iron and their geometric and electronic structure and reactivity.
Cite:
Lyakin O.Y.
, Shteinman A.A.
Oxo Complexes of High-Valence Iron in Oxidation Catalysis
Kinetics and Catalysis. 2012. V.53. N6. P.694-713. DOI: 10.1134/S0023158412050084 WOS Scopus РИНЦ OpenAlex ANCAN
Oxo Complexes of High-Valence Iron in Oxidation Catalysis
Kinetics and Catalysis. 2012. V.53. N6. P.694-713. DOI: 10.1134/S0023158412050084 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Лякин О.Ю.
, Штейнман А.А.
Оксо-комплексы высоковалентного железа в катализе окислительных реакций
Кинетика и катализ. 2012. Т.53. №6. С.738-759. РИНЦ
Оксо-комплексы высоковалентного железа в катализе окислительных реакций
Кинетика и катализ. 2012. Т.53. №6. С.738-759. РИНЦ
Dates:
| Submitted: | Mar 4, 2012 |
| Published print: | Nov 1, 2012 |
| Published online: | Nov 25, 2012 |
Identifiers:
| ≡ Web of science: | WOS:000314455000007 |
| ≡ Scopus: | 2-s2.0-84870498588 |
| ≡ Elibrary: | 20495313 |
| ≡ OpenAlex: | W2004247014 |
| ≡ Chemical Abstracts: | 2012:1724918 |
| ≡ Chemical Abstracts (print): | 157:724129 |