Influence of the Temperature of Calcination of Bayerite-Containing Aluminum Hydroxide Pellets on the Water Vapor Adsorption Capacity and Acid-Base Properties of Alumina Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2012, Volume: 53, Number: 5, Pages: 570-576 Pages count : 7 DOI: 10.1134/S0023158412050187 | ||
| Tags | Calcination Temperature; Boehmite; Gibbsite; Lewis Acid Site; Static Capacity | ||
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Abstract:
The paper considers the influence of the temperature of calcination (350–550°C) of alumina-based water adsorbents prepared from bayerite-containing aluminum hydroxide on the static water sorption capacity at high and low relative air humidities and on the acid-base properties of the surface. The acid-base properties of aluminas have been determined by means of IR spectroscopy of adsorbed CO probe molecule (Lewis sites) and by the spin probe method, which was used to determine the concentrations of electron acceptor and electron donor sites. It has been demonstrated that, at a high relative air humidity (60%), there is no correlation between the static capacity of the drier and its acid-base properties, while at low relative humidities (1–1.5%), an increase in the concentration of electron donor sites and a decrease in the concentration of electron donor and Lewis acid sites enhance the water sorption capacity of alumina.
Cite:
Zotov R.A.
, Glazyrin A.A.
, Danilevich V.V.
, Kharina I.V.
, Zyuzin D.A.
, Volodin A.M.
, Isupova L.A.
Influence of the Temperature of Calcination of Bayerite-Containing Aluminum Hydroxide Pellets on the Water Vapor Adsorption Capacity and Acid-Base Properties of Alumina
Kinetics and Catalysis. 2012. V.53. N5. P.570-576. DOI: 10.1134/S0023158412050187 WOS Scopus РИНЦ OpenAlex ANCAN
Influence of the Temperature of Calcination of Bayerite-Containing Aluminum Hydroxide Pellets on the Water Vapor Adsorption Capacity and Acid-Base Properties of Alumina
Kinetics and Catalysis. 2012. V.53. N5. P.570-576. DOI: 10.1134/S0023158412050187 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Зотов Р.А.
, Глазырин А.В.
, Данилевич В.В.
, Харина И.В.
, Зюзин Д.А.
, Володин А.М.
, Исупова Л.А.
Влияние температуры прокаливания гранул байеритсодержащего гидроксида алюминия на емкость по парам воды и кислотно-основные свойства оксида алюминия
Кинетика и катализ. 2012. Т.53. №5. С.599-606. РИНЦ
Влияние температуры прокаливания гранул байеритсодержащего гидроксида алюминия на емкость по парам воды и кислотно-основные свойства оксида алюминия
Кинетика и катализ. 2012. Т.53. №5. С.599-606. РИНЦ
Dates:
| Submitted: | Mar 17, 2011 |
| Published print: | Sep 1, 2012 |
| Published online: | Sep 27, 2012 |
Identifiers:
| ≡ Web of science: | WOS:000309239200009 |
| ≡ Scopus: | 2-s2.0-84870168636 |
| ≡ Elibrary: | 20492972 |
| ≡ OpenAlex: | W2122012611 |
| ≡ Chemical Abstracts: | 2012:1413103 |
| ≡ Chemical Abstracts (print): | 158:247197 |