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Phase Composition and Structure of Nanocrystalline Products of Solid-Phase Oxidative Thermolysis of Iron Oxalate Dihydrate Full article

Journal Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779
Output data Year: 2012, Volume: 53, Number: 3, Pages: 548-556 Pages count : 9 DOI: 10.1134/S0022476612030195
Tags Debye formula, Iron oxides, Modeling, Nanopowders, Powder X-ray diffraction, Radial distribution function, Structural studies
Authors Yatsenko D.A. 1,3 , Pakharukova V.P. 1,3 , Tsybulya S.V. 1,3 , Matvienko A.A. 2,3 , Sidelʹnikov A.A. 2
Affiliations
1 G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
2 Institute of Solid State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
3 Novosibirsk State University

Funding (2)

1 Siberian Branch of the Russian Academy of Sciences 36
2 The Ministry of Education and Science of the Russian Federation 2.1.1./10165

Abstract: X-ray diffraction studies of the ultradisperse products of the solid-phase oxidative thermolysis of iron oxalate dehydrate are performed. Models are considered and diffraction patterns are calculated for the nanopowders of different crystalline modifications of iron oxide. Calculations are performed for the particles of various shapes and sizes, starting from one unit cell. Despite that the final product is the hematite phase, the reaction is shown to pass through the formation of particles with the ferrihydrite structure.
Cite: Yatsenko D.A. , Pakharukova V.P. , Tsybulya S.V. , Matvienko A.A. , Sidelʹnikov A.A.
Phase Composition and Structure of Nanocrystalline Products of Solid-Phase Oxidative Thermolysis of Iron Oxalate Dihydrate
Journal of Structural Chemistry. 2012. V.53. N3. P.548-556. DOI: 10.1134/S0022476612030195 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Яценко Д.А. , Пахарукова В.П. , Цыбуля С.В. , Матвиенко А.А. , Сидельников А.А.
Фазовый состав и структура нанокристаллических продуктов твердофазного окислительного термолиза дигидрата оксалата железа
Журнал структурной химии. 2012. Т.53. №3. С.554-562. RSCI РИНЦ
Dates:
Submitted: Jul 11, 2011
Published print: May 1, 2012
Published online: Jul 26, 2012
Identifiers:
Web of science: WOS:000306947900019
Scopus: 2-s2.0-84867079859
Elibrary: 19135761
Chemical Abstracts: 2012:1093255
Chemical Abstracts (print): 158:367233
OpenAlex: W2010404728
Citing:
DB Citing
Web of science 13
Scopus 14
Elibrary 16
OpenAlex 14
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