Catalytic Oxidation of α,β- and β,γ-Unsaturated Bicyclic Ketones with Hydrogen Peroxide | Sciact - CRIS-система Института катализа

Catalytic Oxidation of α,β- and β,γ-Unsaturated Bicyclic Ketones with Hydrogen Peroxide Научная публикация

Журнал

Chemistry for Sustainable Development
ISSN: 1817-1818

Вых. Данные

Год: 2008, Том: 16, Номер: 4, Страницы: 413-418 Страниц : 6

Ключевые слова

PHASE TRANSFER CATALYSIS, PEROXOPOLYOXOTUNGSTATES, UNSATURATED BICYCLIC KETONES, EPOXIDES, HYDROGEN PEROXIDE

Авторы

Pai Z.P. ¹ , Berdnikova P.V. ¹ , Nosikov A.A. ² , Khlebnikov B.M. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia)
2	Tomsk Polytechnical University, Pr. Lenina 30, Tomsk 634050 (Russia)

Информация о финансировании (2)

1	Министерство образования и науки Российской Федерации	02.515.11.5009
2	Президиум РАН	5.6.3

For the purpose of utilization of the side products formed in the processes of production of caprolactam, adipinic acid etc. at the stage of liquid-phase oxidation of cyclohexane with atmospheric oxygen, the possibility to oxidize the compounds incorporated into the light-coloured fraction of X-oil - α,β- and β,γ-unsaturated bicyclic ketones - was investigated. Oxidation was carried out using a 30 % hdyrogen peroxide solution at a temperature of 55-65 oC at atmospheric pressure in a two-phase system (aqueous phase - organic phase) in the presence of homogenous bifunctional nanostructurized catalysts based on tetra(oxodiperoxotungsteno)phosphate in combination with quaternary ammonium cations. The analysis of reaction products was carried out by means of GC-MS, TLC and GC.

Pai Z.P. , Berdnikova P.V. , Nosikov A.A. , Khlebnikov B.M.
Catalytic Oxidation of α,β- and β,γ-Unsaturated Bicyclic Ketones with Hydrogen Peroxide
Chemistry for Sustainable Development. 2008. V.16. N4. P.413-418. РИНЦ

Пай З.П. , Бердникова П.В. , Носиков А.А. , Хлебников Б.М.
Каталитическое окисление пероксидом водорода α,β- и β,γ-ненасыщенных бициклических кетонов
Химия в интересах устойчивого развития. 2008. Т.16. №4. С.421-426. РИНЦ CAPlusCA

Поступила в редакцию:	25 окт. 2007 г.
Принята к публикации:	11 июн. 2008 г.

РИНЦ:

20140250

Пока нет цитирований