Hydrodeoxygenation of Biodiesel in the Presence of Catalysts Based on Precious Metals | Sciact - CRIS-система Института катализа

Hydrodeoxygenation of Biodiesel in the Presence of Catalysts Based on Precious Metals Научная публикация

Журнал

Chemistry for Sustainable Development
ISSN: 1817-1818

Вых. Данные

Год: 2009, Том: 17, Номер: 5, Страницы: 521-526 Страниц : 6

Ключевые слова

catalyst, hydrodeoxygen ation, biodiesel fuel, biofuel, methyl esters of fatty acids

Авторы

Dundich V.O. ¹ , Yakovlev V.A. ²

Организации

1	Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090 (Russia)
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences,Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia)

Reaction of the catalytic hydrodeoxygenation of biodiesel - a mixture of methyl esters of fatty acids - is investigated for the purpose of obtaining linear alkanes. Precious metals (Ru, Rh, Pd, Ir, Pt) deposited on the binary oxide system CeO2-ZrO2 were used as catalysts. It is shown that these catalysts allow one to carry out efficient deoxygenation of methyl esters of fatty acids under hydrogen pressure 0.5 MPa within a broad temperature range (300-380 оC) resulting mainly in heptadecane (С17Н36). However, only in the presence of Rh and Ru catalysts the yield of alkanes is quantitative. The process of obtaining linear alkanes of the С14-С18 series using this method is positioned as a stage of production of high-quality kerosene fuel of plant origin.

Dundich V.O. , Yakovlev V.A.
Hydrodeoxygenation of Biodiesel in the Presence of Catalysts Based on Precious Metals
Chemistry for Sustainable Development. 2009. V.17. N5. P.521-526. РИНЦ

Дундич В.О. , Яковлев В.А.
Гидродеоксигенация биодизеля в присутствии катализаторов на основе благородных металлов
Химия в интересах устойчивого развития. 2009. Т.17. №5. С.527-532. RSCI РИНЦ CAPlusCA

Поступила в редакцию:

27 апр. 2009 г.

РИНЦ:

19529222

БД	Цитирований
РИНЦ	7