Investigation of the State of Active Component in Pd/Ga2O3 and Pd/In2O3 Catalysts of Liquid-Phase Hydrogenation of Acetylene into Etylene | Sciact - CRIS-system of Boreskov Institute of Catalysis

Investigation of the State of Active Component in Pd/Ga2O3 and Pd/In2O3 Catalysts of Liquid-Phase Hydrogenation of Acetylene into Etylene Full article

Journal

Chemistry for Sustainable Development
ISSN: 1817-1818

Output data

Year: 2013, Volume: 21, Number: 1, Pages: 91-100 Pages count : 10

Tags

liquid-phase hydrogen ation of acetylene, EXAFS, XPES, TCD, chemisorption of CO; Pd/Ga2O3, Pd/In2O3

Authors

Smirnova N.S. ¹ , Shlyapin D.A. ¹ , Protasova O.V. ¹ , Trenikhin M.V. ¹ , Gulyaeva T.I. ¹ , Gerasimov E.Yu. ² , Kibis L.S. ² , Shitova N.B. ¹ , Kochubey D.I. ² , Tsyrulʹnikov P.G. ¹

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, Ul. Neftezàvodskàya 54, Omsk 644040 (Russia)
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia)

Funding (2)

1	Russian Foundation for Basic Research	10-03-90727
2	The Ministry of Education and Science of the Russian Federation	14.518.11.7022

Catalysts of liquid-phase hydrogenation of acetylene deposited on the oxides of aluminium, gallium, and indium were studied. According to the results of catalytic tests and examination using the physical methods, decoration of the active component by partially reduced support is observed in Pd/Ga2O3 and Pd/In2O3 catalysts. An increase in the atomic catalytic activity for the samples deposited on gallium and indium oxides can be connected with the change of the electron density of the active component or with the formation of bimetallic phases

Smirnova N.S. , Shlyapin D.A. , Protasova O.V. , Trenikhin M.V. , Gulyaeva T.I. , Gerasimov E.Y. , Kibis L.S. , Shitova N.B. , Kochubey D.I. , Tsyrulʹnikov P.G.
Investigation of the State of Active Component in Pd/Ga2O3 and Pd/In2O3 Catalysts of Liquid-Phase Hydrogenation of Acetylene into Etylene
Chemistry for Sustainable Development. 2013. V.21. N1. P.91-100. РИНЦ

Смирнова Н.С. , Шляпин Д.А. , Протасова О.В. , Тренихин М.В. , Гуляева Т.И. , Герасимов Е.Ю. , Кибис Л.С. , Шитова Н.Б. , Кочубей Д.И. , Цырульников П.Г.
Исследование состояния активного компонента в катализаторах Pd/Ga2O3 и Pd/In2O3 жидкофазного гидрирования ацетилена в этилен
Химия в интересах устойчивого развития. 2013. Т.21. №1. С.99-108. РИНЦ ANCAN

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