Abstract: The possibility to use available and easily synthesized borate-containing aluminium oxide as an acidic support for the catalyst of hydroisomerization of benzene-containing gasoline fractions was demonstrated for the first time. The phase composition, texture characteristics and acid properties of B2O3–Al2O3 systems with boron oxide content 0.9–39.0 mass %, obtained by mixing pseudo-boehmite with solid ortho–boric acid followed by annealing at a temperature of 600 °C were studied. For hydroisomerization of the model mixture of n-heptane with benzene it was shown that the most efficient sample is Pt/B2O3–Al2O3 with the support containing 27.5 mass % of boron oxide. This catalyst provides almost complete benzene hydrogenation and the maximal yield of methylcyclopentane (12.1 mass %) and isoheptanes (43.5 mass %) at a temperature of 350 °C. Higher selectivity of isomerization reactions in this case is connected with the smaller amount of strong acid centres on the catalyst surface.

Cite: Fedorova E.D. , Kazakov M.O. , Lavrenov A.V. , Buyalskaya K.S. , Leontyeva N.N. , Gulyaeva T.I. , Shilova A.V.
Optimization of the Composition of Pt/B2O3–Al2O3 Catalyst for Hydroisomerization of Benzene–Containing Fractions
Chemistry for Sustainable Development. 2013. V.21. N1. P.107-113. РИНЦ

Original: Федорова Е.Д. , Казаков М.О. , Лавренов А.В. , Буяльская К.С. , Леонтьева Н.Н. , Гуляева Т.И. , Шилова А.В.
Оптимизация химического состава катализатора Pt/B2O3-Al2O3 для гидроизомеризации бензолсодержащих фракций
Химия в интересах устойчивого развития. 2013. Т.21. №1. С.115-122. РИНЦ ANCAN

Identifiers:

Elibrary:

46563935

Citing:

DB	Citing
Elibrary	1