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Bifunctional Metal Complex Catalysts for the Processes of Fine Organic Synthesis Full article

Journal

Chemistry for Sustainable Development
ISSN: 1817-1818

Output data

Year: 2013, Volume: 21, Number: 3, Pages: 267-277 Pages count : 11

Tags

peroxopolyoxometallates, EXAFS, Raman and IR spectroscopy, phase-transfer catalysts, fine organic synthesis

Authors

Pai Z.P. ¹

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia)

Modern approaches to the development of ecologically and economically acceptable methods for obtaining a number of industrially essential products are considered. The promising character of the application of phase-transfer catalysis method for reactions proceeding in liquid two-phase systems with the use of ecologically favourable oxidizing agent – hydrogen peroxide – was demonstrated. Results of integrated studies of the structural characteristics of tungsten peroxopolyoxocomplexes formed in the interaction of the aqueous solutions of phosphotungstic heteropolyacid with hydrogen peroxide by means of EXAFS, Raman and IR spectroscopy are presented. The synthesized catalysts Q3{PO4[WO(O2)2]4}, where Q3 is a quaternary ammonium cation, were tested in the reactions of oxidation of organic substrates with 30–35 % H2O2 solutions

Pai Z.P.
Bifunctional Metal Complex Catalysts for the Processes of Fine Organic Synthesis
Chemistry for Sustainable Development. 2013. V.21. N3. P.267-277. РИНЦ

Пай З.П.
Бифункциональные металлокомплексные катализаторы для процессов тонкого органического синтеза
Химия в интересах устойчивого развития. 2013. Т.21. №3. С.267-277. RSCI РИНЦ ANCAN

Submitted:

Nov 27, 2012

Elibrary:

30760118

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