Effect of the Acid–Base Properties of Metal Phosphate Molecular Sieves on the Catalytic Performances in Synthesis of Propylene Glycol Methyl Ether from Methanol and Propylene Oxide | Sciact - CRIS-system of Boreskov Institute of Catalysis

Effect of the Acid–Base Properties of Metal Phosphate Molecular Sieves on the Catalytic Performances in Synthesis of Propylene Glycol Methyl Ether from Methanol and Propylene Oxide Full article

Journal

Microporous and Mesoporous Materials
ISSN: 1387-1811 , E-ISSN: 1873-3093

Output data

Year: 2013, Volume: 165, Pages: 84-91 Pages count : 8 DOI: 10.1016/j.micromeso.2012.07.051

Tags

Acid-base properties, Nickel phosphate molecular sieves VSB-5, Propylene glycol methyl ether, Silicoaluminophosphate molecular sieves SAPO-34

Authors

Timofeeva M.N. ^1,2 , Panchenko V.N. ¹ , Jun Jong Won ³ , Hasan Zubair ³ , Kikhtyanin O.V. ¹ , Prosvirin I.P. ¹ , Jhung Sung Hwa ³

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State Technichal University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation
3	Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea

Funding (1)

Kyungpook National University

The aim of this study was to investigate correlation between acid–base and catalytic properties of metal phosphate molecular sieves, such as silicoaluminophosphate molecular sieves SAPO-34 and Fe-substituted nickel phosphate Fe-VSB-5, in the reaction of propylene oxide with methanol. This reaction proceeds in two different ways, depending upon the nature of the samples, and gives rise to either primary and/or secondary alkyl ether of propylene glycol. The results indicate that acid–base properties of Fe-VSB-5 and SAPO-34 materials depend on the Fe and Si content, respectively. The increase in Fe content leads to an increase in basicity of VSB-5, while the increase in Si content favors the increase in acidity of SAPO-34. The strength and amount of Brönsted acid sites of Fe-VSB-5 and SAPO-34 are key factors to control their catalytic activity, while the strength and amounts of Lewis-acid sites and base sites are key factors to control the isomer selectivity

Timofeeva M.N. , Panchenko V.N. , Jun J.W. , Hasan Z. , Kikhtyanin O.V. , Prosvirin I.P. , Jhung S.H.
Effect of the Acid–Base Properties of Metal Phosphate Molecular Sieves on the Catalytic Performances in Synthesis of Propylene Glycol Methyl Ether from Methanol and Propylene Oxide
Microporous and Mesoporous Materials. 2013. V.165. P.84-91. DOI: 10.1016/j.micromeso.2012.07.051 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jun 14, 2012
Accepted:	Jul 31, 2012
Published online:	Aug 8, 2012
Published print:	Jan 1, 2013

Web of science:	WOS:000311070500013
Scopus:	2-s2.0-84865504420
Elibrary:	20415537
Chemical Abstracts:	2012:1579960
Chemical Abstracts (print):	157:608298
OpenAlex:	W2064047290

DB	Citing
Web of science	18
Scopus	19
Elibrary	16
OpenAlex	18