Catalytic Potential of the Wonderful Chameleons: Nickel Phosphate Molecular Sieves Review
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2013, Volume: 455, Pages: 71- 85 Pages count : 15 DOI: 10.1016/j.apcata.2013.01.019 | ||||||
| Tags | Acid-base, Catalytic properties, Nickel phosphate molecular sieves, Red-ox, Review, VSB-1, VSB-5 | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | The Ministry of Education and Science of the Russian Federation | 2012-1.5-12-000-1013-002 |
| 2 | National Research Foundation of Korea | 2012R1A1A2004528 |
Abstract:
This review is devoted to the discoveries and knowledge developed in the past 10–15 years in the area of the design and applications of nickel phosphate molecular sieves (VSB-1 and VSB-5). The main textural and physicochemical characteristics of these materials that make them suitable for catalysis were viewed at the molecular and atomic levels. According to various spectroscopic investigations, the type of metal ions introduced into the VSB-1 and VSB-5 framework allows one to adjust the nature of the surface functional groups and thereby, affects the catalytic properties. Emphasis is placed upon the relationship between the physicochemical properties and their catalytic properties in hydrogenation, oxidation and acid–base type reactions. Because of the simultaneous existence of acid–base and red-ox pairs, nickel phosphate molecular sieves, similar to a chameleon, can adapt to catalytic systems and provide necessary active sites. This review clearly demonstrates that nickel phosphate molecular sieves (VSB-n series) possess promising catalytic properties: e.g., shape selectivity, red-ox and acid–base catalysis, and we expect that this work opens the door to novel applications of these materials in catalysis.
Cite:
Timofeeva M.N.
, Panchenko V.N.
, Hasan Z.
, Jhung S.H.
Catalytic Potential of the Wonderful Chameleons: Nickel Phosphate Molecular Sieves
Applied Catalysis A: General. 2013. V.455. P.71- 85. DOI: 10.1016/j.apcata.2013.01.019 WOS Scopus РИНЦ ANCAN OpenAlex
Catalytic Potential of the Wonderful Chameleons: Nickel Phosphate Molecular Sieves
Applied Catalysis A: General. 2013. V.455. P.71- 85. DOI: 10.1016/j.apcata.2013.01.019 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 7, 2012 |
| Accepted: | Jan 16, 2013 |
| Published online: | Feb 9, 2013 |
| Published print: | Mar 30, 2013 |
Identifiers:
| Web of science: | WOS:000318391500010 |
| Scopus: | 2-s2.0-84875990933 |
| Elibrary: | 20430936 |
| Chemical Abstracts: | 2013:554014 |
| Chemical Abstracts (print): | 158:486584 |
| OpenAlex: | W2062477203 |