Реферат: The composition and structure of neutral and acid trialkyl(C8-C10)methylammonium acetates in CCl4+HAc solutions formed by the reaction R3CH3N+Ac−+nHAc⇔R3CH3N+(Ac·nAc)− are investigated by IR spectroscopy. As the molar ratio HAc/R3CH3N+Ac− increases in solutions, complex anions Ac·nAc− (I) with n=1, 2, 3, 4 are formed in sequence. The curves of formation of anions with n=0, 1, 2 are plotted. One terminal COO group of anions I is bonded to (“blocked” by) the R3CH3N+ cation, and another group sequentially adds H-bonded HAc molecules as the concentration of HAc in solutions increases. The sequence of IR spectral changes in the series of anions I with n=0, 1, 2, 3, 4 is discussed.

Библиографическая ссылка: Stoyanov E.S. , Chesalov Y.A.
Composition, Structure, and IR Spectra of Acid Trialkylmethylammonium Acetates in CCl4 +HAc Solutions
Journal of Structural Chemistry. 1996. V.37. N2. P.270-277. DOI: 10.1007/BF02591057 WOS Scopus РИНЦ OpenAlex

Оригинальная: Стоянов Е.С. , Чесалов Ю.А.
Состав, строение и особенности ик спектров кислых ацетатов триалкилметиламмония в растворах ССl4 + НАc
Журнал структурной химии. 1996. Т.37. №2. С.310-318. РИНЦ CAPlusCA

Даты:

Поступила в редакцию:	5 апр. 1995 г.
Опубликована в печати:	1 мар. 1996 г.

Идентификаторы БД:

Web of science:	WOS:A1996VL83500015
Scopus:	2-s2.0-27544435884
РИНЦ:	29848189
OpenAlex:	W2018276124

Цитирование в БД:

БД	Цитирований
Web of science	1
Scopus	1
OpenAlex	1

Альметрики: