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Detailed XPS and UPS Studies of the Band Structure of Zinc Oxide Full article

Journal Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779
Output data Year: 1997, Volume: 38, Number: 5, Pages: 725-731 Pages count : 7 DOI: 10.1007/BF02763884
Tags Zinc Oxide Photoelectron Spectrum Quantum Energy Integral Intensity Ratio Photoelectron Emission
Authors Leontʹev S.A. 1 , Koshcheev S.V. 1 , Devyatov V.G. 1 , Cherkashin A.E. 1 , Mikheeva E.P. 1
Affiliations
1 G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Abstract: The X-ray photoelectron spectra of zinc oxide were measured in a wide range of quantum energies (30–150 and 1253.6 eV). It is shown that the form of the spectrum of the valence O2p-band depends on the energy of the incident quantum. The most probable reason for the change in the form of the O2p-band spectra is an admixture of Zn3d-electrons, which, along with Zn4s-electronst take part in covalent bonding of Zn and O. The dependence of the integral intensity ratio of the O2p-band to the intensity of the Zn3d peak on hv was analyzed, due to which the percent of the admixture of the Zn3d-states in the O2p-band was determined to be 9%. The stoichiometry and the depth of the profile of the concentration ratio were calculated taking into account the fraction of the Zn3d-electrons participating in the bond.
Cite: Leontʹev S.A. , Koshcheev S.V. , Devyatov V.G. , Cherkashin A.E. , Mikheeva E.P.
Detailed XPS and UPS Studies of the Band Structure of Zinc Oxide
Journal of Structural Chemistry. 1997. V.38. N5. P.725-731. DOI: 10.1007/BF02763884 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Леонтьев С.А. , Кощеев С.В. , Девятов В.Г. , Черкашин А.Е. , Михеева Э.П.
Детальное изучение зонной структуры оксида цинка методами РФЭС и УФЭС СИ
Журнал структурной химии. 1997. Т.38. №5. С.868-876. РИНЦ
Dates:
Submitted: Jan 9, 1997
Published print: Sep 1, 1997
Identifiers:
Web of science: WOS:000073247600006
Scopus: 2-s2.0-22044439235
Elibrary: 13250164
Chemical Abstracts: 1998:273391
Chemical Abstracts (print): 129:10021
OpenAlex: W2035915054
Citing:
DB Citing
Web of science 25
Scopus 25
Elibrary 26
OpenAlex 31
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