Detailed XPS and UPS Studies of the Band Structure of Zinc Oxide Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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Output data | Year: 1997, Volume: 38, Number: 5, Pages: 725-731 Pages count : 7 DOI: 10.1007/BF02763884 | ||
Tags | Zinc Oxide Photoelectron Spectrum Quantum Energy Integral Intensity Ratio Photoelectron Emission | ||
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Abstract:
The X-ray photoelectron spectra of zinc oxide were measured in a wide range of quantum energies (30–150 and 1253.6 eV). It is shown that the form of the spectrum of the valence O2p-band depends on the energy of the incident quantum. The most probable reason for the change in the form of the O2p-band spectra is an admixture of Zn3d-electrons, which, along with Zn4s-electronst take part in covalent bonding of Zn and O. The dependence of the integral intensity ratio of the O2p-band to the intensity of the Zn3d peak on hv was analyzed, due to which the percent of the admixture of the Zn3d-states in the O2p-band was determined to be 9%. The stoichiometry and the depth of the profile of the concentration ratio were calculated taking into account the fraction of the Zn3d-electrons participating in the bond.
Cite:
Leontʹev S.A.
, Koshcheev S.V.
, Devyatov V.G.
, Cherkashin A.E.
, Mikheeva E.P.
Detailed XPS and UPS Studies of the Band Structure of Zinc Oxide
Journal of Structural Chemistry. 1997. V.38. N5. P.725-731. DOI: 10.1007/BF02763884 WOS Scopus РИНЦ ANCAN OpenAlex
Detailed XPS and UPS Studies of the Band Structure of Zinc Oxide
Journal of Structural Chemistry. 1997. V.38. N5. P.725-731. DOI: 10.1007/BF02763884 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Леонтьев С.А.
, Кощеев С.В.
, Девятов В.Г.
, Черкашин А.Е.
, Михеева Э.П.
Детальное изучение зонной структуры оксида цинка методами РФЭС и УФЭС СИ
Журнал структурной химии. 1997. Т.38. №5. С.868-876. РИНЦ
Детальное изучение зонной структуры оксида цинка методами РФЭС и УФЭС СИ
Журнал структурной химии. 1997. Т.38. №5. С.868-876. РИНЦ
Dates:
Submitted: | Jan 9, 1997 |
Published print: | Sep 1, 1997 |
Identifiers:
Web of science: | WOS:000073247600006 |
Scopus: | 2-s2.0-22044439235 |
Elibrary: | 13250164 |
Chemical Abstracts: | 1998:273391 |
Chemical Abstracts (print): | 129:10021 |
OpenAlex: | W2035915054 |