Chemo- and Stereoselective C-H Oxidations and Epoxidations/cis-Dihydroxylations with H2O2, Catalyzed by Non-Heme Iron and Manganese Complexes Review
| Journal |
Coordination Chemistry Reviews
ISSN: 0010-8545 , E-ISSN: 1873-3840 |
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| Output data | Year: 2012, Volume: 256, Number: 13-14, Pages: 1418-1434 Pages count : 17 DOI: 10.1016/j.ccr.2012.04.005 | ||
| Tags | Active sites, Asymmetric, Epoxidation, Hydrocarbons, Hydrogen peroxide, Iron, Manganese, Mechanism, Non-heme, Oxidation | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 12-03-00782 |
Abstract:
The discovery of simple and efficient catalyst systems for the selective oxofunctionalization of hydrocarbons is a challenging task of modern chemistry. The biomimetic approach, which aims at mimicking the reactivity of natural enzymes in catalyzed transformation with synthetic low-molecular weight compounds, has been widely applied to the search for new transition metal based catalyst systems in the last two decades. In effect, numerous iron and manganese complexes modeling the catalytic performance of non-heme metal-containing monooxygenases have been reported and intensively investigated. In this contribution, non-heme iron- and manganese catalyzed selective oxidations of alkanes, as well as chemo- and stereoselective epoxidations and cis-dihydroxylations of alkenes, using H2O2 as the oxygen source, are reviewed, with major focus on the their synthetic potential. Recent experimental investigations of the nature of catalytically active species and mechanisms of their action are summarized.
Cite:
Talsi E.P.
, Bryliakov K.P.
Chemo- and Stereoselective C-H Oxidations and Epoxidations/cis-Dihydroxylations with H2O2, Catalyzed by Non-Heme Iron and Manganese Complexes
Coordination Chemistry Reviews. 2012. V.256. N13-14. P.1418-1434. DOI: 10.1016/j.ccr.2012.04.005 WOS Scopus РИНЦ ANCAN OpenAlex
Chemo- and Stereoselective C-H Oxidations and Epoxidations/cis-Dihydroxylations with H2O2, Catalyzed by Non-Heme Iron and Manganese Complexes
Coordination Chemistry Reviews. 2012. V.256. N13-14. P.1418-1434. DOI: 10.1016/j.ccr.2012.04.005 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Feb 7, 2012 |
| Accepted: | Apr 3, 2012 |
| Published online: | Apr 11, 2012 |
| Published print: | Jul 1, 2012 |
Identifiers:
| Web of science: | WOS:000305037200005 |
| Scopus: | 2-s2.0-84860888705 |
| Elibrary: | 17985138 |
| Chemical Abstracts: | 2012:612541 |
| Chemical Abstracts (print): | 157:548033 |
| OpenAlex: | W2062482634 |