Synthesis, Crystal Structure and Thermal Properties of [Co(NH3 )5 Cl]MO4 (M = Mo, W) | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis, Crystal Structure and Thermal Properties of [Co(NH3 )5 Cl]MO4 (M = Mo, W) Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2011, Volume: 52, Number: 5, Pages: 918-923 Pages count : 6 DOI: 10.1134/S0022476611050118

Tags

Cobalt, Complex salt, Crystal chemistry, Molybdenum, Single crystal X-ray diffraction, Thermal properties, Tungsten

Authors

Shusharina E.A. ¹ , Khranenko S.P. ¹ , Plyusnin P.E. ^1,3 , Kardash T.Y. ² , Gromilov S.A. ^1,3

Affiliations

1	A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
2	G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk
3	Novosibirsk State University, SEC “Nanosystems and Advanced Materials”

Funding (3)

1	Russian Foundation for Basic Research	11-03-00668
2	Siberian Branch of the Russian Academy of Sciences	112
3	The Ministry of Education and Science of the Russian Federation	П960

Crystal structures of [Co(NH3)5Cl]MoO4 and [Co(NH3)5Cl]WO4 complex salts are determined by single crystal X-ray diffraction. It is demonstrated for both salts that within the temperature range T = −123−20°C there is a negative thermal expansion (about 0.26%) towards the c axis of the orthorhombic unit cell (Pnma space group). Thermal properties of the salts are investigated. The phase composition of the products obtained on heating the salts in different gas atmospheres is studied.

Shusharina E.A. , Khranenko S.P. , Plyusnin P.E. , Kardash T.Y. , Gromilov S.A.
Synthesis, Crystal Structure and Thermal Properties of [Co(NH3 )5 Cl]MO4 (M = Mo, W)
Journal of Structural Chemistry. 2011. V.52. N5. P.918-923. DOI: 10.1134/S0022476611050118 WOS Scopus РИНЦ ANCAN OpenAlex

Шушарина Е.А. , Храненко С.П. , Плюснин П.Е. , Кардаш Т.Ю. , Громилов С.А.
[Со(NH3)5Cl]MO4 (M = Мо, W): синтез, кристаллическая структура, термические свойства
Журнал структурной химии. 2011. Т.52. №5. С.946-951. RSCI РИНЦ

Submitted:	Nov 19, 2010
Published print:	Oct 1, 2011
Published online:	Nov 30, 2011

Web of science:	WOS:000298861300011
Scopus:	2-s2.0-84856201892
Elibrary:	18034290
Chemical Abstracts:	2011:1539432
Chemical Abstracts (print):	156:45846
OpenAlex:	W2014917232

DB	Citing
Web of science	6
Scopus	6
Elibrary	6
OpenAlex	6