Crystal Structure and Thermal Properties of [Au(en)2]2[Cu(C2O4 )2]3·8H2O Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
||||||
|---|---|---|---|---|---|---|---|
| Output data | Year: 2011, Volume: 52, Number: 5, Pages: 924-929 Pages count : 6 DOI: 10.1134/S002247661105012X | ||||||
| Tags | Copper, Crystal chemistry, Ethylenediamine, Gold, Oxalate ion, Thermal analysis, X-ray crystallography | ||||||
| Authors |
|
||||||
| Affiliations |
|
Funding (3)
| 1 | Russian Foundation for Basic Research | 11-03-00668 |
| 2 | Siberian Branch of the Russian Academy of Sciences | 112 |
| 3 | The Ministry of Education and Science of the Russian Federation | П999 |
Abstract:
The crystal structure of a double complex salt of the composition [Au(en)2]2[Cu(C2O4)2]3·8H2O (en = ethylenediamine) at 150 K is determined by single crystal X-ray diffraction. The crystal data for C20H48Au2Cu3N8O32 are: a = 9.1761(3) Å, b = 16.9749(6) Å, c = 13.4475(5) Å, β = 104.333(1)°, V = 2029.43(12) Å3, P21/c space group, Z = 2, d x = 2.450 g/cm3. It is demonstrated that the thermal decomposition of the double complex salt in a helium or hydrogen atmosphere affords the solid solution Au0.4Cu0.6.
Cite:
Makotchenko E.V.
, Bykova E.A.
, Semitut E.Y.
, Shubin Y.V.
, Snytnikov P.V.
, Plyusnin P.E.
Crystal Structure and Thermal Properties of [Au(en)2]2[Cu(C2O4 )2]3·8H2O
Journal of Structural Chemistry. 2011. V.52. N5. P.924-929. DOI: 10.1134/S002247661105012X WOS Scopus РИНЦ ANCAN OpenAlex
Crystal Structure and Thermal Properties of [Au(en)2]2[Cu(C2O4 )2]3·8H2O
Journal of Structural Chemistry. 2011. V.52. N5. P.924-929. DOI: 10.1134/S002247661105012X WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Макотченко Е.В.
, Быкова Е.А.
, Семитут Е.Ю.
, Шубин Ю.В.
, Снытников П.В.
, Плюснин П.Е.
Кристаллическая структура и термические свойства [Au(en)2]2[Cu(C2O4)2]3 • 8H2O
Журнал структурной химии. 2011. Т.52. №5. С.952-957. RSCI РИНЦ
Кристаллическая структура и термические свойства [Au(en)2]2[Cu(C2O4)2]3 • 8H2O
Журнал структурной химии. 2011. Т.52. №5. С.952-957. RSCI РИНЦ
Dates:
| Submitted: | Dec 14, 2010 |
| Published print: | Oct 1, 2011 |
| Published online: | Nov 30, 2011 |
Identifiers:
| Web of science: | WOS:000298861300012 |
| Scopus: | 2-s2.0-84856145333 |
| Elibrary: | 18034216 |
| Chemical Abstracts: | 2011:1539418 |
| Chemical Abstracts (print): | 156:324703 |
| OpenAlex: | W2084677283 |