Frontiers of Mechanistic Studies of Coordination Polymerization and Oligomerization of α-Olefins Review
| Journal |
Coordination Chemistry Reviews
ISSN: 0010-8545 , E-ISSN: 1873-3840 |
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|---|---|---|---|
| Output data | Year: 2012, Volume: 256, Number: 23-24, Pages: 2994-3007 Pages count : 14 DOI: 10.1016/j.ccr.2012.06.023 | ||
| Tags | α-Olefins, Coordination polymerization, Late transition metals, Living polymerization, Propagating species, Reaction mechanisms, Single-site, Tetramerization, Trimerization | ||
| Authors |
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| Affiliations |
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Funding (4)
| 1 | Russian Foundation for Basic Research | 09-03-00485 |
| 2 | Russian Foundation for Basic Research | 10-03-91330 |
| 3 | Russian Foundation for Basic Research | 12-03-00133 |
| 4 | German Research Foundation | Me 1388/9-1 |
Abstract:
Homogeneous single-site alkene polymerization is a “mature” field. However, this does not imply that interestto this research area fades. Moreover, armed by well understood fundamentals of single-site polymerization,
researchers get more and more detailed mechanistic data, important for the improvement of the existing catalyst systems, and rational design of new effective catalysts. This review aims at summarizing the new results obtained over the last few years in unraveling the mechanisms of coordination polymerization of ˛-olefins and selective oligomerization of ethylene. It is mainly focused on isospecific polymerization, living polymerization, polymerization by late transition metal complexes, and selective trimerization and tetramerization of ethylene
Cite:
Bryliakov K.P.
, Talsi E.P.
Frontiers of Mechanistic Studies of Coordination Polymerization and Oligomerization of α-Olefins
Coordination Chemistry Reviews. 2012. V.256. N23-24. P.2994-3007. DOI: 10.1016/j.ccr.2012.06.023 WOS Scopus РИНЦ ANCAN OpenAlex
Frontiers of Mechanistic Studies of Coordination Polymerization and Oligomerization of α-Olefins
Coordination Chemistry Reviews. 2012. V.256. N23-24. P.2994-3007. DOI: 10.1016/j.ccr.2012.06.023 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Apr 6, 2012 |
| Accepted: | Jun 20, 2012 |
| Published online: | Jun 30, 2012 |
| Published print: | Dec 1, 2012 |
Identifiers:
| Web of science: | WOS:000313475000012 |
| Scopus: | 2-s2.0-84869500981 |
| Elibrary: | 20494820 |
| Chemical Abstracts: | 2012:1037713 |
| Chemical Abstracts (print): | 158:132030 |
| OpenAlex: | W1973798007 |