Hofmeister Anion Effect on the Formation of Zeolite Beta Full article
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4th International FEZA Conference 02-06 Sep 2008 , Paris |
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| Source | Zeolites and related materials: Trends, targets and challenges: Proceedings of the 4th International FEZA Conference, 2-6 September 2008, Paris, France Compilation, 2008. 1387 c. ISBN 9780444532985. |
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| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Output data | Year: 2008, Volume: 174, Number: A, Pages: 167-172 Pages count : 6 DOI: 10.1016/S0167-2991(08)80169-3 | ||
| Tags | Beta zeolite, Hofmeister series, synthesis | ||
| Authors |
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Abstract:
Influence of the anion X nature in tetraethylammonium compound [N(C2H5)4]X used as SDA in the non-seeded “SiO2 – Al2O3 – Na2O – [N(C2H5)4]X – H2O” reacting system on Beta zeolite formation selectivity was investigated. On the base of crystallization product phase composition as a function of synthesis time, the studied series of anions
may be arranged in the following sequence: F¯, SO42-, PO43-, (CH2COO)22- > HCOO¯ >(COO)22-, CH3COO¯ >> Cl¯ ~ NO3¯ >> Br¯ >> I¯ >> ClO4¯ with decreasing zeolite Beta formation potency from left to right . Particularly, F-
, SO42-, PO43- and succinate anions facilitate formation of Beta zeolite in a wide range of the reaction gel chemical
composition, while ClO4¯, I¯, Br¯ anions prevent the zeolite crystallization. It was experimentally showed that “zeolite-promoting” anions allow to crystallize Beta zeolite in the same wide range of Si/Al composition as it is in TEAOH system, as well as to synthesize the substituted versions of Beta zeolite. The found sequence generally
coincides with the well-known Hofmeister series of anions.
Cite:
Tokarev A.V.
, Echevsky G.V.
Hofmeister Anion Effect on the Formation of Zeolite Beta
In compilation Zeolites and related materials: Trends, targets and challenges: Proceedings of the 4th International FEZA Conference, 2-6 September 2008, Paris, France. 2008. – Т.Part A. – C.167-172. – ISBN 9780444532985. DOI: 10.1016/S0167-2991(08)80169-3 WOS Scopus РИНЦ ANCAN OpenAlex
Hofmeister Anion Effect on the Formation of Zeolite Beta
In compilation Zeolites and related materials: Trends, targets and challenges: Proceedings of the 4th International FEZA Conference, 2-6 September 2008, Paris, France. 2008. – Т.Part A. – C.167-172. – ISBN 9780444532985. DOI: 10.1016/S0167-2991(08)80169-3 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 2008 |
| Published online: | Nov 19, 2008 |
Identifiers:
| Web of science: | WOS:000283749900024 |
| Scopus: | 2-s2.0-56049122691 |
| Elibrary: | 13581796 |
| Chemical Abstracts: | 2009:245974 |
| Chemical Abstracts (print): | 154:413100 |
| OpenAlex: | W1568079726 |