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A New Concept Reactor for Hydrocarbon Hydrogenation in the Reactive Evaporation Mode Full article

Conference Catalysis in Multiphase Reactors : 4th International symposium
22-25 Sep 2002 , Lausanne
Journal Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Output data Year: 2003, Volume: 79-80, Pages: 105-111 Pages count : 7 DOI: 10.1016/S0920-5861(03)00016-6
Tags Evaporation, Hydrocarbon hydrogenation, Imbibition, Non-permselective membrane, Novel multiphase reactor, Sintered metal catalyst support
Authors Kuzin N.A. 1 , Kulikov A.V. 1 , Shigarov A.B. 1 , Kirillov V.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Prosp. Akad. Lavrentieva 5, 630090 Novosibirsk, Russia

Abstract: A new gas–liquid–solid reactor is presented whose concept is based on the coupling of liquid imbibition, evaporation, and an exothermic gas-phase reaction within a non-permselective catalytic porous membrane. Because of enhanced thermal conductivity of the sintered metal catalyst support and liquid flow re-circulation, it is possible to eliminate hot spots and runaways and to maintain high productivity of the reactor. When vapor conversion in the membrane is high, the problem of separation of the product from the gas phase reduces to common condensation. The preliminary experiments on the alfa-methylstyrene (AMS) hydrogenation on the 10% (0.9% Pd/-Al2O3) + 90% (80% Ni, 20% Al) membrane sintered on the tube wall are very promising, however, further investigations are required.
Cite: Kuzin N.A. , Kulikov A.V. , Shigarov A.B. , Kirillov V.A.
A New Concept Reactor for Hydrocarbon Hydrogenation in the Reactive Evaporation Mode
Catalysis Today. 2003. V.79-80. P.105-111. DOI: 10.1016/S0920-5861(03)00016-6 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Mar 16, 2003
Published print: Apr 30, 2003
Identifiers:
Web of science: WOS:000183016500015
Scopus: 2-s2.0-0037544221
Elibrary: 13436775
Chemical Abstracts: 2003:364163
Chemical Abstracts (print): 139:166141
OpenAlex: W1998562251
Citing:
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Web of science 5
Scopus 5
Elibrary 7
OpenAlex 5
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