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Impact of Phase Composition on Water Adsorption on Inorganic Hybrids “Salt/Silica” ArticleGenre_short.SHORT_COMMUNICATION

Journal Journal of Colloid and Interface Science
ISSN: 0021-9797 , E-ISSN: 1095-7103
Output data Year: 2006, Volume: 301, Number: 2, Pages: 685-691 Pages count : 7 DOI: 10.1016/j.jcis.2006.05.009
Tags Composites "salt/silica", Inorganic salts, Mesoporous silica gel, Metal cation adsorption, Surface interaction, Water adsorption
Authors Gordeeva Larisa G. 1 , Glaznev Ivan S. 1 , Savchenko Elena V. 1 , Malakhov Vladislav V. 1 , Aristov Yuri I. 1
Affiliations
1 Boreskov Institute of Catalysis, Ac. Lavrentiev Ave. 5, Novosibirsk 630090, Russia

Funding (3)

1 Russian Foundation for Basic Research 04-02-81028
2 Russian Foundation for Basic Research 05-02-16953
3 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union 2003-51-6260

Abstract: The effect of a “guest–host” interaction on the phase composition and sorption properties of the composite sorbents “salt in a porous host matrix” has been studied. The matrix was a mesoporous silica of KSK type, while the confined salts were CaCl2, CuSO4, MgSO4, and Na2SO4. Both structure and properties of the composites were studied by X-ray diffraction, titration in the pH range of 2–9, differential dissolution, and TG techniques. Chemical interaction between the silica surface and the salt during preparation results in the formation of the salt surface complexes and stabilization of the dispersed salt in two phases, namely, a crystalline phase and an X-ray amorphous phase. The water sorption properties of the composites depend on the phase composition and can be intently modified by using variation of the preparation conditions.
Cite: Gordeeva L.G. , Glaznev I.S. , Savchenko E.V. , Malakhov V.V. , Aristov Y.I.
Impact of Phase Composition on Water Adsorption on Inorganic Hybrids “Salt/Silica”
Journal of Colloid and Interface Science. 2006. V.301. N2. P.685-691. DOI: 10.1016/j.jcis.2006.05.009 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
Submitted: Mar 1, 2006
Accepted: May 4, 2006
Published online: Jun 12, 2006
Published print: Sep 15, 2006
Identifiers:
Web of science: WOS:000239937700046
Scopus: 2-s2.0-33746913552
Elibrary: 13515555
Chemical Abstracts: 2006:802843
Chemical Abstracts (print): 145:426726
PMID: 16765372
OpenAlex: W2011733229
Citing:
DB Citing
Web of science 60
Scopus 67
Elibrary 68
OpenAlex 69
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