Mechanism of Iso-Butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39, and Zr Supported Catalysts Научная публикация
| Конференция |
12th International Congress on Catalysis 09-14 июл. 2000 , Granada |
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| Сборник | 12th International Congress on Catalysis : Proceedings of the 12th ICC
9-14 July 2000, Granada, Spain Сборник, 2000. 3940 c. ISBN 9780444504807. |
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| Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Вых. Данные | Год: 2000, Том: 130, Номер: Part C, Номер статьи : P268, Страниц : 6 DOI: 10.1016/S0167-2991(00)80852-6 | ||
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| Организации |
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Реферат:
In the present paper we report on the mechanism of i-butane alkylation by butenes using three types of well defined catalysts. The first type catalysts are composed heteropolyacids supported on a carbon support. The second type catalysts are represented by sulfated zirconia supported on silica. The third type catalysts were prepared with molecular design using alkyl zirconium complexes. Zirconium cations in coordinatively unsaturated state are shown to be responsible for alkylation. Reaction mechanism is suggested, involving carbenium ions and zirconium hydrides generation from i-butane.
Библиографическая ссылка:
Paukshtis E.A.
, Duplyakin V.K.
, Finevich V.P.
, Lavrenov A.V.
, Kirillov V.L.
, Kuznetsova L.I.
, Likholobov V.A.
, Balʹzhinimaev B.S.
Mechanism of Iso-Butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39, and Zr Supported Catalysts
В сборнике 12th International Congress on Catalysis : Proceedings of the 12th ICC 9-14 July 2000, Granada, Spain. 2000. – C.2543-2548. – ISBN 9780444504807. DOI: 10.1016/S0167-2991(00)80852-6 Scopus РИНЦ CAPlusCA OpenAlex
Mechanism of Iso-Butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39, and Zr Supported Catalysts
В сборнике 12th International Congress on Catalysis : Proceedings of the 12th ICC 9-14 July 2000, Granada, Spain. 2000. – C.2543-2548. – ISBN 9780444504807. DOI: 10.1016/S0167-2991(00)80852-6 Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 2000 г. |
| Опубликована online: | 2 сент. 2007 г. |
Идентификаторы БД:
| Scopus: | 2-s2.0-0034350771 |
| РИНЦ: | 13358368 |
| Chemical Abstracts: | 2000:566821 |
| Chemical Abstracts (print): | 133:254626 |
| OpenAlex: | W2086999634 |