Direct Insertion of Methane into C3–C4 Paraffins over Zeolite Catalysts: A Start to the Development of New One-Step Catalytic Processes for the Gas-to-Liquid Transformation Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2004, Volume: 258, Number: 2, Pages: 159-171 Pages count : 13 DOI: 10.1016/j.apcata.2003.08.024 | ||||
| Tags | Aromatization, Methane, One-step insertion, Zeolite | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Council for Grants of the President of the Russian Federation | НШ-1484.2003.3 |
| 2 | The Ministry of Education and Science of the Russian Federation | 3H-23-00 |
Abstract:
The paper demonstrates that utilization of the well-known concept of the ability of the same catalytic centers to catalyze both forward and backward reactions can result in the development of a process of the direct one-step insertion of methane into heavier hydrocarbons. The insertion seems to proceed as a part of linear alkanes dehydrocyclization reactions at rather mild pressure and temperature conditions (at 773–823 K) over Zn- or Ga-promoted zeolite catalysts. The experimental study of the process evidences in its potential practical applicability for the natural gas-to-liquid conversion.
Cite:
Echevsky G.V.
, Kodenev E.G.
, Kikhtyanin O.V.
, Parmon V.N.
Direct Insertion of Methane into C3–C4 Paraffins over Zeolite Catalysts: A Start to the Development of New One-Step Catalytic Processes for the Gas-to-Liquid Transformation
Applied Catalysis A: General. 2004. V.258. N2. P.159-171. DOI: 10.1016/j.apcata.2003.08.024 WOS Scopus РИНЦ ANCAN OpenAlex
Direct Insertion of Methane into C3–C4 Paraffins over Zeolite Catalysts: A Start to the Development of New One-Step Catalytic Processes for the Gas-to-Liquid Transformation
Applied Catalysis A: General. 2004. V.258. N2. P.159-171. DOI: 10.1016/j.apcata.2003.08.024 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Apr 10, 2003 |
| Accepted: | Aug 27, 2003 |
| Published online: | Jan 17, 2004 |
| Published print: | Feb 20, 2004 |
Identifiers:
| Web of science: | WOS:000188969600004 |
| Scopus: | 2-s2.0-0742286903 |
| Elibrary: | 13458625 |
| Chemical Abstracts: | 2004:86190 |
| Chemical Abstracts (print): | 140:341081 |
| OpenAlex: | W2003037229 |