Oxidative Addition of Dihydrogen to the Bimetallic Sulfide Catalysts: Evidence by X-Ray Photoelectron Spectroscopy Full article
| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2000, Volume: 151, Number: 1-2, Pages: 171-177 Pages count : 7 DOI: 10.1016/S1381-1169(99)00237-X | ||
| Tags | Oxidative addition of hydrogen, Sulfide HDS catalysts, X-ray photoelectron spectroscopy | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 97-03-32568 |
Abstract:
Reversible transformations Ni(IV)↔Ni(II) in alumina and Sibunit supported (Ni,Mo) sulfide catalysts were observed after in situ thermal treatment of catalysts in an X-ray photoelectron spectrometer chamber. The phenomenon is interpreted as a reductive elimination of occluded hydrogen under low pressure and high temperature, and oxidative addition of hydrogen after catalyst treatment with an (H2+H2S) mixture.
Cite:
Startsev A.N.
, Kalinkin A.V.
, Zakharov I.I.
, Aksenov D.G.
, Parmon V.N.
Oxidative Addition of Dihydrogen to the Bimetallic Sulfide Catalysts: Evidence by X-Ray Photoelectron Spectroscopy
Journal of Molecular Catalysis A: Chemical. 2000. V.151. N1-2. P.171-177. DOI: 10.1016/S1381-1169(99)00237-X WOS Scopus РИНЦ ANCAN OpenAlex
Oxidative Addition of Dihydrogen to the Bimetallic Sulfide Catalysts: Evidence by X-Ray Photoelectron Spectroscopy
Journal of Molecular Catalysis A: Chemical. 2000. V.151. N1-2. P.171-177. DOI: 10.1016/S1381-1169(99)00237-X WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 26, 1999 |
| Accepted: | May 19, 1999 |
| Published online: | Feb 14, 2000 |
| Published print: | Feb 15, 2000 |
Identifiers:
| Web of science: | WOS:000085386100016 |
| Scopus: | 2-s2.0-0034651646 |
| Elibrary: | 13351249 |
| Chemical Abstracts: | 2000:118137 |
| Chemical Abstracts (print): | 132:168447 |
| OpenAlex: | W2022789126 |