Linalool Synthesis from α-Pinene: Kinetic Peculiarities of Catalytic Steps Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2001, Volume: 211, Number: 1, Pages: 91-107 Pages count : 17 DOI: 10.1016/S0926-860X(00)00841-3 | ||
| Tags | Aromatic compounds; Catalyst selectivity; Hydrogenation; Isomerization; Oxidation; Reaction kinetics; Synthesis (chemical) | ||
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Abstract:
Synthesis of linalool from α-pinene which includes consecutively α-pinene hydrogenation to pinane on Pd/C catalyst, pinane oxidation to pinane-hydroperoxide by molecular oxygen and pinane-hydroperoxide hydrogenation to pinanol on Pd/C catalyst followed by its thermal isomerization to linalool is discussed. The effects of the reagent concentrations, temperature and catalyst content on the reaction rate and selectivity are studied. The kinetic peculiarities and the mechanisms of reactions are presented. The synthetic conditions of high-selective linalool preparation are found.
Cite:
Semikolenov V.A.
, Ilʹina I.I.
, Simakova I.L.
Linalool Synthesis from α-Pinene: Kinetic Peculiarities of Catalytic Steps
Applied Catalysis A: General. 2001. V.211. N1. P.91-107. DOI: 10.1016/S0926-860X(00)00841-3 WOS Scopus РИНЦ ANCAN OpenAlex
Linalool Synthesis from α-Pinene: Kinetic Peculiarities of Catalytic Steps
Applied Catalysis A: General. 2001. V.211. N1. P.91-107. DOI: 10.1016/S0926-860X(00)00841-3 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Mar 21, 2000 |
| Accepted: | Oct 31, 2000 |
| Published online: | Mar 7, 2001 |
| Published print: | Mar 16, 2001 |
Identifiers:
| Web of science: | WOS:000167626600009 |
| Scopus: | 2-s2.0-0035278461 |
| Elibrary: | 13374066 |
| Chemical Abstracts: | 2001:177560 |
| Chemical Abstracts (print): | 135:5711 |
| OpenAlex: | W2061399244 |