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XPS, TPD and TPR Studies of Cs–O Complexes on Silver: Their Role in Ethylene Epoxidation Full article

Conference Physical Methods for Catalytic Research at the Molecular Level: International memorial K.I. Zamaraev conference
28 Jun - 2 Jul 1999 , Novosibirsk
Journal Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169
Output data Year: 2000, Volume: 158, Number: 1, Pages: 337-343 Pages count : 7 DOI: 10.1016/S1381-1169(00)00101-1
Tags Cs-O complexes, Ethylene epoxidation, Silver, XPS
Authors Podgornov E.A. 1 , Prosvirin I.P. 1 , Bukhtiyarov V.I. 1
Affiliations
1 Boreskov Institute of Catalysis, SB RAS, Lavrentieva 5, 630090 Novosibirsk, Russia

Abstract: Various Cs oxides formed on the Ag(111) and Ag(110) single crystals depending on cesium coverage, oxygen pressure have been identified by XPS and TPD. The comparison of the determined characteristics with the data for the Ag/Al2O3 catalysts allows us to select those of the Cs–O structures which are common for both types of samples: cesium peroxide and cesium suboxide. Mechanisms of their influence onto routes of ethylene oxidation are discussed.
Cite: Podgornov E.A. , Prosvirin I.P. , Bukhtiyarov V.I.
XPS, TPD and TPR Studies of Cs–O Complexes on Silver: Their Role in Ethylene Epoxidation
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.337-343. DOI: 10.1016/S1381-1169(00)00101-1 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Jul 18, 2000
Published print: Sep 8, 2000
Identifiers:
Web of science: WOS:000089201200044
Scopus: 2-s2.0-0034623143
Elibrary: 13353141
Chemical Abstracts: 2000:498705
Chemical Abstracts (print): 133:281406
OpenAlex: W2069216235
Citing:
DB Citing
Web of science 56
Scopus 60
Elibrary 59
OpenAlex 57
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