Kinetic Peculiarities of α-Pinene Oxidation by Molecular Oxygen Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2004, Volume: 272, Number: 1-2, Pages: 109-114 Pages count : 6 DOI: 10.1016/j.apcata.2004.05.020 | ||
| Tags | α-Pinene oxidation, Kinetics, Mechanism, Verbenol synthesis, Verbenyl-hydroperoxide hydrogenation on Pd/C | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Civilian Research and Development Foundation | NO-008-X1 |
Abstract:
Kinetic peculiarities of α-pinene liquid-phase oxidation by molecular oxygen were studied (in a temperature range of 343–393 K and at oxygen pressure within 0.5–6 bar range). The process proceeds selectively at a low α-pinene conversion and the main products are verbenyl-hydroperoxide and α-pinene epoxide. The products ratio depends slightly on temperature, oxygen pressure and α-pinene conversion. The kinetic equation for the reaction rate was suggested.
Cite:
Ancel J.E.
, Maksimchuk N.V.
, Simakova I.L.
, Semikolenov V.A.
Kinetic Peculiarities of α-Pinene Oxidation by Molecular Oxygen
Applied Catalysis A: General. 2004. V.272. N1-2. P.109-114. DOI: 10.1016/j.apcata.2004.05.020 WOS Scopus РИНЦ ANCAN OpenAlex
Kinetic Peculiarities of α-Pinene Oxidation by Molecular Oxygen
Applied Catalysis A: General. 2004. V.272. N1-2. P.109-114. DOI: 10.1016/j.apcata.2004.05.020 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 14, 2004 |
| Accepted: | May 14, 2004 |
| Published online: | Jul 20, 2004 |
| Published print: | Sep 1, 2004 |
Identifiers:
| Web of science: | WOS:000223592700012 |
| Scopus: | 2-s2.0-3843049056 |
| Elibrary: | 13458113 |
| Chemical Abstracts: | 2004:671069 |
| Chemical Abstracts (print): | 141:331712 |
| OpenAlex: | W2026746245 |