Active Metal Species Assembled with Heteropoly Tungstate Anion PW9O349− for Liquid Phase Hydrocarbon Oxidation Full article
| Conference |
Physical Methods for Catalytic Research at the Molecular Level: International memorial K.I. Zamaraev conference 28 Jun - 2 Jul 1999 , Novosibirsk |
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| Journal |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2000, Volume: 158, Number: 1, Pages: 429-433 Pages count : 5 DOI: 10.1016/S1381-1169(00)00118-7 | ||
| Tags | 183W, 51V, Benzene oxidation, Heteropolycomplexes, NMR 31P, O2/H2 mixture, Palladium(II) | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 96-15-97557 |
Abstract:
Monometallic [Pd3(PW9O34)2]12−, [Pd3(PW9O34)2PdnOxHy ]q− (where on the average n=3), bimetallic [Pd2Cu(PW9O34)2]12−, [Pd2Fe(PW9O34)2]11−, [PdFe2(PW9O34)2]10− and a mixture of [Pd3(PW9O34)2PdnOxHy]q− (nav≈10)+[(VO)3(PW9O34)2]9− complexes were prepared and characterized by NMR 31P, 183W, 51V and IR spectroscopy. The complexes were tested in catalysis of O2+H2 reaction and benzene oxidation to phenol with O2/H2. Effectiveness of the catalytic performance depended on the composition of the complexes. Bimetallic Pd(II)–Fe(III) complexes were several times more active in phenol production than Pd(II) monometallic systems.
Cite:
Kuznetsova L.I.
, Kuznetsova N.I.
, Detusheva L.G.
, Fedotov M.A.
, Likholobov V.A.
Active Metal Species Assembled with Heteropoly Tungstate Anion PW9O349− for Liquid Phase Hydrocarbon Oxidation
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.429-433. DOI: 10.1016/S1381-1169(00)00118-7 WOS Scopus РИНЦ ANCAN OpenAlex
Active Metal Species Assembled with Heteropoly Tungstate Anion PW9O349− for Liquid Phase Hydrocarbon Oxidation
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.429-433. DOI: 10.1016/S1381-1169(00)00118-7 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Jul 18, 2000 |
| Published print: | Sep 8, 2000 |
Identifiers:
| Web of science: | WOS:000089201200061 |
| Scopus: | 2-s2.0-0034622702 |
| Elibrary: | 13346024 |
| Chemical Abstracts: | 2000:498722 |
| Chemical Abstracts (print): | 133:340898 |
| OpenAlex: | W1980072454 |