Role of Defect Structure in Structural Sensitivity of the Oxidation Reactions Catalyzed by Dispersed Transition Metal Oxides Научная публикация
| Конференция |
Physical Methods for Catalytic Research at the Molecular Level: International memorial K.I. Zamaraev conference 28 июн. - 2 июл. 1999 , Novosibirsk |
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| Журнал |
Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Вых. Данные | Год: 2000, Том: 158, Номер: 1, Страницы: 361-365 Страниц : 5 DOI: 10.1016/S1381-1169(00)00105-9 | ||
| Ключевые слова | Defects, Oxidation reactions, Structural sensitivity, Transition metal oxides | ||
| Авторы |
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| Организации |
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Реферат:
For dispersed transition metal oxides, the specific catalytic activity in the reactions of CO and hydrocarbons oxidation was compared with the densities of bulk and surface defects that were estimated using a combination of diffraction and spectroscopic methods. On this basis, the oxide systems were classified with respect to the scale and origin of the structural sensitivity manifestation. The results were discussed from the point of view of the atomic structure of the most developed surface faces of these oxides and their stoichiometry ranges. The most active surface sites were found to be associated with the surface extended defects including those located at the outlets of bulk extended defects.
Библиографическая ссылка:
Sadykov V.A.
, Tikhov S.F.
, Tsybulya S.V.
, Kryukova G.N.
, Veniaminov S.A.
, Kolomiichuk V.N.
, Bulgakov N.N.
, Paukshtis E.A.
, Ivanov V.P.
, Koshcheev S.V.
, Zaikovskii V.I.
, Isupova L.A.
, Burgina E.B.
Role of Defect Structure in Structural Sensitivity of the Oxidation Reactions Catalyzed by Dispersed Transition Metal Oxides
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.361-365. DOI: 10.1016/S1381-1169(00)00105-9 WOS Scopus РИНЦ CAPlusCA OpenAlex
Role of Defect Structure in Structural Sensitivity of the Oxidation Reactions Catalyzed by Dispersed Transition Metal Oxides
Journal of Molecular Catalysis A: Chemical. 2000. V.158. N1. P.361-365. DOI: 10.1016/S1381-1169(00)00105-9 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована online: | 18 июл. 2000 г. |
| Опубликована в печати: | 8 сент. 2000 г. |
Идентификаторы БД:
| Web of science: | WOS:000089201200048 |
| Scopus: | 2-s2.0-6744224426 |
| РИНЦ: | 13343072 |
| Chemical Abstracts: | 2000:498709 |
| Chemical Abstracts (print): | 133:199276 |
| OpenAlex: | W1969412955 |