Reaction of Butyraldehyde Formation from Ethylene and Ethylene Oxide on ZSM-5 Surface Научная публикация
| Журнал |
Research on Chemical Intermediates
ISSN: 0922-6168 , E-ISSN: 1568-5675 |
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| Вых. Данные | Год: 2015, Том: 41, Номер: 11, Страницы: 8735-8745 Страниц : 11 DOI: 10.1007/s11164-015-1925-5 | ||||
| Ключевые слова | Butyraldehyde formation, Ethylene, Ethylene oxide, Product extraction, ZSM-5 zeolite | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский фонд фундаментальных исследований | 14-03-31402 |
Реферат:
A recently discovered surface reaction of ethylene oxide (EO) with ethylene yielding butyraldehyde (BA) was studied on ZSM-5 zeolites with different contents of Al, Na, and Fe in the temperature range of −25 to 100 °C. Products formed on a zeolite as a result of EO and ethylene transformations were extracted from the surface and identified using gas chromatography, gas chromatography–mass spectrometry, and nuclear magnetic resonance. In addition to BA, the other major reaction products are acetaldehyde and dioxane. Product distribution strongly depends on the composition of the zeolite samples and experimental conditions. Varying of the Al content in the zeolites as well as their temperature pretreatment showed that a key role in the formation of BA play dehydroxylated Al-contained sites. Possible transformations of EO and ethylene on the zeolite were analyzed by quantum-chemical calculations.
Библиографическая ссылка:
Parfenov M.V.
, Malykhin S.E.
, Pirutko L.V.
, Kharitonov A.S.
, Starokon E.V.
Reaction of Butyraldehyde Formation from Ethylene and Ethylene Oxide on ZSM-5 Surface
Research on Chemical Intermediates. 2015. V.41. N11. P.8735-8745. DOI: 10.1007/s11164-015-1925-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Reaction of Butyraldehyde Formation from Ethylene and Ethylene Oxide on ZSM-5 Surface
Research on Chemical Intermediates. 2015. V.41. N11. P.8735-8745. DOI: 10.1007/s11164-015-1925-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 12 нояб. 2014 г. |
| Принята к публикации: | 8 янв. 2015 г. |
| Опубликована online: | 27 февр. 2015 г. |
| Опубликована в печати: | 1 нояб. 2015 г. |
Идентификаторы БД:
| Web of science: | WOS:000362896400050 |
| Scopus: | 2-s2.0-84944165696 |
| РИНЦ: | 24961260 |
| Chemical Abstracts: | 2015:355699 |
| Chemical Abstracts (print): | 163:489620 |
| OpenAlex: | W2013390100 |