Selective CO Methanation in H2-Rich Stream over Ni–, Co– and Fe/CeO2: Effect of Metal and Precursor Nature Full article
| Conference |
2nd International Congress on Energy Efficiency and Energy Related Materials 16-19 Oct 2014 , Oludeniz |
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| Journal |
International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487 |
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| Output data | Year: 2015, Volume: 40, Number: 40, Pages: 14058-14063 Pages count : 6 DOI: 10.1016/j.ijhydene.2015.07.071 | ||||
| Tags | Carbon monoxide removal, CO clean up, Effect of chlorine, Ni, Co, Fe/CeO<inf>2</inf> catalysts, Preferential CO methanation, Selective CO methanation | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 14-03-00457 |
| 2 | The Ministry of Education and Science of the Russian Federation |
Abstract:
Selective CO methanation in the realistic H2-rich gas mixture containing 10 vol.% H2O and 20 vol.% CO2 was investigated over 10 wt.% Ni–, Co– and Fe/CeO2 catalysts, prepared from nitrate and chloride precursors. BET, XRD, HRTEM, EDX and CO chemisorption techniques were used for catalyst characterization. Among the catalysts studied, the Ni/CeO2 catalyst, prepared from NiCl2 precursor, showed the best catalytic performance. This phenomenon can be associated with inhibition of CO2 hydrogenation activity by the presence of chlorine on the catalyst surface.
Cite:
Konishcheva M.V.
, Potemkin D.I.
, Snytnikov P.V.
, Zyryanova M.M.
, Pakharukova V.P.
, Simonov P.A.
, Sobyanin V.A.
Selective CO Methanation in H2-Rich Stream over Ni–, Co– and Fe/CeO2: Effect of Metal and Precursor Nature
International Journal of Hydrogen Energy. 2015. V.40. N40. P.14058-14063. DOI: 10.1016/j.ijhydene.2015.07.071 WOS Scopus РИНЦ ANCAN OpenAlex
Selective CO Methanation in H2-Rich Stream over Ni–, Co– and Fe/CeO2: Effect of Metal and Precursor Nature
International Journal of Hydrogen Energy. 2015. V.40. N40. P.14058-14063. DOI: 10.1016/j.ijhydene.2015.07.071 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jan 28, 2015 |
| Accepted: | Jul 14, 2015 |
| Published online: | Aug 6, 2015 |
| Published print: | Oct 1, 2015 |
Identifiers:
| Web of science: | WOS:000363080200022 |
| Scopus: | 2-s2.0-84942984113 |
| Elibrary: | 24957648 |
| Chemical Abstracts: | 2015:1263514 |
| Chemical Abstracts (print): | 163:430036 |
| OpenAlex: | W1051249732 |