State of Iron in Nanoparticles Prepared by Impregnation of Silica Gel and Aluminum Oxide with FeSO4 Solutions Full article
| Journal |
Physics of the Solid State
ISSN: 1063-7834 , E-ISSN: 1090-6460 |
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| Output data | Year: 2010, Volume: 52, Number: 4, Pages: 826-837 Pages count : 12 DOI: 10.1134/S1063783410040268 | ||||
| Tags | Quadrupole Splitting; Hexagonal Packing; Divalent Iron; Nonequivalent Position; Oxysulfate | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Президиум РАН | 46 |
Abstract:
The state of iron in nanoparticles prepared by impregnating silica gel and aluminum oxide with iron(II) sulfate solutions has been investigated using Mössbauer spectroscopy. It has been revealed that the state of iron depends on the nature of the support. Iron(III) hydroxysulfate and iron(III) oxysulfate nanoparticles are formed on the surface of silica gel, and iron oxide nanoparticles are formed on the surface of aluminum oxide. An increase in the concentration of iron ions or in the size of iron-containing particles leads to hydration of the nanoparticle surface. The calcination of the samples results in the formation of ɛ-Fe2O3 oxide in a strongly disordered or amorphous state in iron-containing particles on the surface of silica gel.
Cite:
Bukhtiyarova G.A.
, Martyanov O.N.
, Yakushkin S.S.
, Kazakova (Shuvaeva) M.A.
, Bayukov O.A.
State of Iron in Nanoparticles Prepared by Impregnation of Silica Gel and Aluminum Oxide with FeSO4 Solutions
Physics of the Solid State. 2010. V.52. N4. P.826-837. DOI: 10.1134/S1063783410040268 WOS Scopus РИНЦ OpenAlex ANCAN
State of Iron in Nanoparticles Prepared by Impregnation of Silica Gel and Aluminum Oxide with FeSO4 Solutions
Physics of the Solid State. 2010. V.52. N4. P.826-837. DOI: 10.1134/S1063783410040268 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Бухтиярова Г.А.
, Мартьянов О.Н.
, Якушкин С.С.
, Казакова М.А.
, Баюков О.А.
Состояние железа в наночастицах, полученных методом пропитки силикагеля и оксида алюминия раствором FeSO4
Физика твердого тела. 2010. Т.52. №4. С.771-781. РИНЦ
Состояние железа в наночастицах, полученных методом пропитки силикагеля и оксида алюминия раствором FeSO4
Физика твердого тела. 2010. Т.52. №4. С.771-781. РИНЦ
Dates:
| Submitted: | Jul 16, 2009 |
| Published print: | Apr 1, 2010 |
| Published online: | Apr 27, 2010 |
Identifiers:
| ≡ Web of science: | WOS:000277098200026 |
| ≡ Scopus: | 2-s2.0-77951724038 |
| ≡ Elibrary: | 15332072 |
| ≡ OpenAlex: | W2068933858 |
| ≡ Chemical Abstracts: | 2010:519141 |
| ≡ Chemical Abstracts (print): | 153:583825 |