Formation of Active State in Vanadium–Titanium Oxide System Regarding to Reaction of Oxidation of β-Picoline to Nicotinic Acid Научная публикация
| Конференция |
Innovation in Selective Oxidation by Solid Catalysts : 6th European Workshop on Selective Oxidation 09-10 сент. 1999 , Rimini |
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| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2000, Том: 61, Номер: 1-4, Страницы: 249-254 Страниц : 6 DOI: 10.1016/S0920-5861(00)00376-X | ||
| Ключевые слова | Vanadium–titanium oxide system; b-Picoline; Nicotinic acid | ||
| Авторы |
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| Организации |
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Реферат:
Binary vanadia–titania catalysts comprising 5–75 wt.% of V2O5 and 95–25 wt.% of TiO2, pretreated at the temperature ranging between 300 and 700°C, were studied as heterogeneous catalysts for oxidation of β-picoline at 250°C, and inlet concentrations of the following components (vol.%): 1% of 3-picoline, 20% of oxygen, 30% of steam. Nicotinic acid, 3-pyridinecarbaldehyde and CO2 were the reaction products. The most active state for oxidation of 3-picoline into nicotinic acid was shown to result from formation of coherent interface between V2O5 and TiO2 (anatase) crystallites. This state was generated at the temperature particular for each composition and persists below the temperature of the anatase to rutile transition.
Библиографическая ссылка:
Alkayeva E.M.
, Andrushkevich T.V.
, Zenkovets G.A.
, Kryukova G.N.
, Tsybulya S.V.
Formation of Active State in Vanadium–Titanium Oxide System Regarding to Reaction of Oxidation of β-Picoline to Nicotinic Acid
Catalysis Today. 2000. V.61. N1-4. P.249-254. DOI: 10.1016/S0920-5861(00)00376-X WOS Scopus РИНЦ CAPlusCA OpenAlex
Formation of Active State in Vanadium–Titanium Oxide System Regarding to Reaction of Oxidation of β-Picoline to Nicotinic Acid
Catalysis Today. 2000. V.61. N1-4. P.249-254. DOI: 10.1016/S0920-5861(00)00376-X WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 10 авг. 2000 г. |
| Опубликована online: | 7 сент. 2000 г. |
Идентификаторы БД:
| Web of science: | WOS:000089455900034 |
| Scopus: | 2-s2.0-0034247934 |
| РИНЦ: | 13336697 |
| Chemical Abstracts: | 2000:619519 |
| Chemical Abstracts (print): | 133:326121 |
| OpenAlex: | W2060481496 |