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Vibrational Spectra of WO3·nH2O and WO3 Polymorphs Full article

Journal Vibrational Spectroscopy
ISSN: 0924-2031
Output data Year: 2011, Volume: 55, Number: 2, Pages: 235-240 Pages count : 6 DOI: 10.1016/j.vibspec.2010.12.004
Tags Infrared spectra, Phase transitions, Raman, Sampling techniques, WO3 hydrates and polymorphs
Authors Kustova G.N. 1 , Chesalov Yu.A. 1 , Plyasova L.M. 1 , Molina I.Y. 1 , Nizovskii A.I. 1
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk, Russia

Abstract: Vibrational spectra of polycrystalline WO3 hydrates and polymorphs were measured and analyzed. The effect of sampling techniques on IR spectra has been demonstrated. The phase transition into triclinic polymorph (C52 h → C1i) has been revealed for the sample of monoclinic WO3 prepared as KBr pellet. Using the deuteration method in situ has shown that cubic WO3 is non-stoichiometric oxide stabilized by residual OH groups of WO3·H2O precursor.
Cite: Kustova G.N. , Chesalov Y.A. , Plyasova L.M. , Molina I.Y. , Nizovskii A.I.
Vibrational Spectra of WO3·nH2O and WO3 Polymorphs
Vibrational Spectroscopy. 2011. V.55. N2. P.235-240. DOI: 10.1016/j.vibspec.2010.12.004 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Apr 29, 2010
Accepted: Dec 3, 2010
Published online: Dec 15, 2010
Published print: Mar 1, 2011
Identifiers:
Web of science: WOS:000288524600013
Scopus: 2-s2.0-79951723952
Elibrary: 16733263
Chemical Abstracts: 2011:212398
Chemical Abstracts (print): 154:375195
OpenAlex: W1984365474
Citing:
DB Citing
Web of science 51
Scopus 49
Elibrary 47
OpenAlex 53
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