Abstract: The experimental methods of X-ray and ultraviolet photoelectron spectroscopies (XPS and UPS, respectively) and the quantum mechanical calculations are applied for analysis of oxygen states on the silver oxide surface. At low temperatures (T<470 K), the silver surface is intensively oxidized by a microwave oxygen discharge to form cuprite Ag2O. Two adsorbed oxygen species of the atomic (dissociative) and molecular (associative) nature can be adsorbed on the cuprite Ag2O surface. A comparison of the UPS data and the DFT calculations of molecular models Ag2–O2 and Ag2–O3 shows that the formation of ozonide-like structures is preferable to that of peroxide species. Thermal stability and the reaction probability of the adsorbed states are investigated.

Cite: Boronin A.I. , Koshcheev S.V. , Murzakhmetov K.T. , Avdeev V.I. , Zhidomirov G.M.
Associative Oxygen Species on the Oxidized Silver Surface Formed under O2 Microwave Excitation
Applied Surface Science. 2000. V.165. N1. P.9-14. DOI: 10.1016/S0169-4332(00)00146-X WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Nov 18, 1999
Accepted:	Feb 10, 2000
Published online:	Jul 18, 2000
Published print:	Sep 15, 2000

Identifiers:

Web of science:	WOS:000088757600002
Scopus:	2-s2.0-0034273924
Elibrary:	13349017
Chemical Abstracts:	2000:488985
Chemical Abstracts (print):	133:272089
OpenAlex:	W1972370345

Citing:

DB	Citing
Web of science	55
Scopus	55
Elibrary	56
OpenAlex	51

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