Abstract: Experimental study of the reaction of heterogeneous decomposition of the hydrogen sulfide on bulk oxides γ-Al2O3, α-Fe2O3 and V2O5 in the interval of temperatures 500–900°C have been performed. Reaction orders by H2S for γ-Al2O3 and V2O5 are 2.0, and for α-Fe2O3 — 2.6; effective activation energies are respectively 72, 94 and Full-size image (<1 K). Using the ESDR and XRD methods, it is shown that in the course of hydrogen sulfide decomposition reaction, the reduction of transition metal oxide catalysts (α-Fe2O3 and V2O5) and also the formation of sulfides under the influence of reaction media proceed. Interaction of hydrogen sulfide with aluminum oxide at low temperatures leads to formation of adsorbed species of H2S as fragments HS− and S2−, which upon heating 100–700°C transfer into different species of sulfur: c-S8, c-S12, S4. In separate experiments it was demonstrated that the higher the temperature of H2S interaction with Al2O3, the larger number of adsorbed sulfur species are observed in the spectra. Molecular hydrogen sulfide interacts with the Al2O3 surface with formation compounds of sulfur with oxygen, which later transform into the final reaction product — elemental sulfur.

Cite: Reshetenko T.V. , Khajrulin S.R. , Ismagilov Z.R. , Kuznetsov V.V.
Study of the Reaction of High-Temperature H2S Decomposition on Metal Oxides (γ-Al2O3, α-Fe2O3, V2O5)
International Journal of Hydrogen Energy. 2002. V.27. N4. P.387-394. DOI: 10.1016/S0360-3199(01)00143-4 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Published online:	Oct 30, 2001
Published print:	Apr 1, 2002

Identifiers:

Web of science:	WOS:000174003300005
Scopus:	2-s2.0-0036533128
Elibrary:	13390662
Chemical Abstracts:	2002:135006
Chemical Abstracts (print):	136:173386
OpenAlex:	W2090311108

Citing:

DB	Citing
Web of science	99
Scopus	107
Elibrary	106
OpenAlex	101

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