Hydrogen Peroxide and Oxygen–Hydrogen Oxidation of Aromatic Compounds in Catalytic Systems Containing Heteropoly Compounds | Sciact - CRIS-system of Boreskov Institute of Catalysis

Hydrogen Peroxide and Oxygen–Hydrogen Oxidation of Aromatic Compounds in Catalytic Systems Containing Heteropoly Compounds Full article

Conference

1st European Conference on Environmental Applications of Advanced Oxidation Processes
07-09 Sep 2006 , Chania-Crete

Journal

Journal of Hazardous Materials
ISSN: 0304-3894 , E-ISSN: 1873-3336

Output data

Year: 2007, Volume: 146, Number: 3, Pages: 569-576 Pages count : 8 DOI: 10.1016/j.jhazmat.2007.04.058

Tags

Benzene, Heteropolycompounds, Oxidation, Phenol, Toluene

Authors

Kuznetsova N.I. ¹ , Kirillova N.V. ¹ , Kuznetsova L.I. ¹ , Smirnova M.Y. ² , Likholobov V.A. ²

Affiliations

1	Boreskov Institute of Catalysis, Lavrentieva, 5, 630090 Novosibirsk, Russian Federation
2	Institute of Hydrocarbon Processing, Neftezavodskaya, 54, 644040, Omsk, Russian Federation

Hydrogen peroxide and Pt activated mixture of gaseous O2 and H2 have been applied to oxidation of aromatic compounds in the presence of redox active heteropoly compounds in the form of acid H4PMo11VO40 and tetrabuthylammonium (TBA) salts TBA4PMo11VO40 and TBA4HPW11Fe(OH)O39. Benzene, toluene and phenol were subjected to hydroxylation of the ring, which was accompanied by secondary oxidation in the reaction with hydrogen peroxide. Oxygenation of toluene was equally directed to the ring and to methyl group. The total reactivity of substrates was increased in the order of benzene < toluene < phenol in oxidation by both O2/H2 and H2O2. Analysis of products yield and composition indicated the identical nature of active intermediates for both oxidants. It was suggested that HPC bonded radical species are responsible for the oxidation of hydrocarbons.

Kuznetsova N.I. , Kirillova N.V. , Kuznetsova L.I. , Smirnova M.Y. , Likholobov V.A.
Hydrogen Peroxide and Oxygen–Hydrogen Oxidation of Aromatic Compounds in Catalytic Systems Containing Heteropoly Compounds
Journal of Hazardous Materials. 2007. V.146. N3. P.569-576. DOI: 10.1016/j.jhazmat.2007.04.058 WOS Scopus РИНЦ ANCAN PMID OpenAlex

Published online:	Apr 20, 2007
Published print:	Jul 31, 2007

Web of science:	WOS:000248524500023
Scopus:	2-s2.0-34347334374
Elibrary:	13552876
Chemical Abstracts:	2007:740936
Chemical Abstracts (print):	147:365194
PMID:	17532134
OpenAlex:	W2023169464

DB	Citing
Web of science	33
Scopus	37
Elibrary	36
OpenAlex	32