Hydrogen Peroxide and Oxygen–Hydrogen Oxidation of Aromatic Compounds in Catalytic Systems Containing Heteropoly Compounds Full article
| Conference |
1st European Conference on Environmental Applications of Advanced Oxidation Processes 07-09 Sep 2006 , Chania-Crete |
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| Journal |
Journal of Hazardous Materials
ISSN: 0304-3894 , E-ISSN: 1873-3336 |
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| Output data | Year: 2007, Volume: 146, Number: 3, Pages: 569-576 Pages count : 8 DOI: 10.1016/j.jhazmat.2007.04.058 | ||||
| Tags | Benzene, Heteropolycompounds, Oxidation, Phenol, Toluene | ||||
| Authors |
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Abstract:
Hydrogen peroxide and Pt activated mixture of gaseous O2 and H2 have been applied to oxidation of aromatic compounds in the presence of redox active heteropoly compounds in the form of acid H4PMo11VO40 and tetrabuthylammonium (TBA) salts TBA4PMo11VO40 and TBA4HPW11Fe(OH)O39. Benzene, toluene and phenol were subjected to hydroxylation of the ring, which was accompanied by secondary oxidation in the reaction with hydrogen peroxide. Oxygenation of toluene was equally directed to the ring and to methyl group. The total reactivity of substrates was increased in the order of benzene < toluene < phenol in oxidation by both O2/H2 and H2O2. Analysis of products yield and composition indicated the identical nature of active intermediates for both oxidants. It was suggested that HPC bonded radical species are responsible for the oxidation of hydrocarbons.
Cite:
Kuznetsova N.I.
, Kirillova N.V.
, Kuznetsova L.I.
, Smirnova M.Y.
, Likholobov V.A.
Hydrogen Peroxide and Oxygen–Hydrogen Oxidation of Aromatic Compounds in Catalytic Systems Containing Heteropoly Compounds
Journal of Hazardous Materials. 2007. V.146. N3. P.569-576. DOI: 10.1016/j.jhazmat.2007.04.058 WOS Scopus РИНЦ OpenAlex ANCAN PMID
Hydrogen Peroxide and Oxygen–Hydrogen Oxidation of Aromatic Compounds in Catalytic Systems Containing Heteropoly Compounds
Journal of Hazardous Materials. 2007. V.146. N3. P.569-576. DOI: 10.1016/j.jhazmat.2007.04.058 WOS Scopus РИНЦ OpenAlex ANCAN PMID
Dates:
| Published online: | Apr 20, 2007 |
| Published print: | Jul 31, 2007 |
Identifiers:
| ≡ Web of science: | WOS:000248524500023 |
| ≡ Scopus: | 2-s2.0-34347334374 |
| ≡ Elibrary: | 13552876 |
| ≡ OpenAlex: | W2023169464 |
| ≡ Chemical Abstracts: | 2007:740936 |
| ≡ Chemical Abstracts (print): | 147:365194 |
| ≡ PMID: | 17532134 |