Preparation and Catalytic Study of Metal Modified TS-1 in the Oxidation of Benzene to Phenol by N2O Научная публикация
Журнал |
Microporous and Mesoporous Materials
ISSN: 1387-1811 , E-ISSN: 1873-3093 |
||||
---|---|---|---|---|---|
Вых. Данные | Год: 2001, Том: 48, Номер: 1-3, Страницы: 345-353 Страниц : 9 DOI: 10.1016/S1387-1811(01)00351-1 | ||||
Ключевые слова | α-sites, Benzene to phenol oxidation, Fe-TS-1, Metal modified TS-1, Nitrous oxide, TS-1 | ||||
Авторы |
|
||||
Организации |
|
Реферат:
The titanosilicalite TS-1 samples modified by Al, V, Cr, Fe, Co and Ru were synthesized, characterized and tested in the title reaction. As with the earlier studied zeolite systems, Fe introduction into the TS-1 matrix produces α-sites that can catalyze the oxidation of benzene to phenol with high activity and selectivity. Other metals are shown to be inert. The quantitative dependencies of the catalytic activity on Fe content and on α-site concentration are discussed.
Библиографическая ссылка:
Pirutko L.V.
, Uriarte A.
, Chernyavsky V.S.
, Kharitonov A.S.
, Panov G.I.
Preparation and Catalytic Study of Metal Modified TS-1 in the Oxidation of Benzene to Phenol by N2O
Microporous and Mesoporous Materials. 2001. V.48. N1-3. P.345-353. DOI: 10.1016/S1387-1811(01)00351-1 WOS Scopus РИНЦ CAPlusCA OpenAlex
Preparation and Catalytic Study of Metal Modified TS-1 in the Oxidation of Benzene to Phenol by N2O
Microporous and Mesoporous Materials. 2001. V.48. N1-3. P.345-353. DOI: 10.1016/S1387-1811(01)00351-1 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: | 6 авг. 2000 г. |
Принята к публикации: | 12 февр. 2001 г. |
Опубликована online: | 16 окт. 2001 г. |
Опубликована в печати: | 1 нояб. 2001 г. |
Идентификаторы БД:
Web of science: | WOS:000171908700043 |
Scopus: | 2-s2.0-0035504137 |
РИНЦ: | 13366962 |
Chemical Abstracts: | 2001:780138 |
Chemical Abstracts (print): | 136:87460 |
OpenAlex: | W2059933145 |