Location, Stability, and Reactivity of Oxygen Species Generated by N2O Decomposition over Fe-ZSM-5 and Fe-Beta Zeolites Full article
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Journal of Molecular Catalysis A: Chemical
ISSN: 1381-1169 |
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| Output data | Year: 2011, Volume: 347, Number: 1-2, Pages: 22-27 Pages count : 6 DOI: 10.1016/j.molcata.2011.07.004 | ||||
| Tags | Fe-Beta, Fe-ZSM-5, Isotope exchange, N2O decomposition, Oxygen species | ||||
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Abstract:
Reactivity of oxygen species generated by N2O decomposition over Fe-ZSM-5 and Fe-Beta zeolites was investigated using oxygen isotopic exchange as test reaction. The generated species are very stable up to 300 °C in the absence of the organic traces or residual N2O in the gas phase. The reactivity of the oxygen species towards organics depends on the size of the organic molecules and their ability to penetrate into the zeolite pores. For example, in case of Fe-ZSM-5 zeolite, the oxygen species react readily with toluene, but stay intact with more bulky 1,3,5-trimethylbenzene.
Cite:
Sobolev V.I.
, Koltunov K.Y.
Location, Stability, and Reactivity of Oxygen Species Generated by N2O Decomposition over Fe-ZSM-5 and Fe-Beta Zeolites
Journal of Molecular Catalysis A: Chemical. 2011. V.347. N1-2. P.22-27. DOI: 10.1016/j.molcata.2011.07.004 WOS Scopus РИНЦ ANCAN OpenAlex
Location, Stability, and Reactivity of Oxygen Species Generated by N2O Decomposition over Fe-ZSM-5 and Fe-Beta Zeolites
Journal of Molecular Catalysis A: Chemical. 2011. V.347. N1-2. P.22-27. DOI: 10.1016/j.molcata.2011.07.004 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | May 6, 2011 |
| Accepted: | Jul 7, 2011 |
| Published online: | Jul 18, 2011 |
| Published print: | Aug 1, 2011 |
Identifiers:
| Web of science: | WOS:000295299900004 |
| Scopus: | 2-s2.0-80052266666 |
| Elibrary: | 18003153 |
| Chemical Abstracts: | 2011:1099209 |
| Chemical Abstracts (print): | 155:460299 |
| OpenAlex: | W2055333608 |